Propyl 6-hydroxynaphthalene-2-carboxylate | 17295-13-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: Propyl 6-hydroxynaphthalene-2-carboxylate
• CAS: 17295-13-5
• 化学式: C₁₄H₁₄O₃
• 分子量: 230.26
• InChiKey: GATKPCVDORJBKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Method of producing thermotropic liquid crystalline polyester
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP0520428A2

  公开（公告）日：1992-12-30

  A thermotropic liquid crystalline polyester is produced by carrying out polycondensation of ester monomer [I-2], an aromatic dicarboxylic acid [II] and an aromatic carboxylic acid [III-2]. The amounts of the compounds [I-2] and [II] are substantially equivalent and the amount of the compound [III-2] is not more than 20 times that of [I-2] by mole. A thermotropic liquid crystalline polyester having good heat resistance, fluidity and uniformity can be produced.

  通过酯单体[I-2]、芳香族二羧酸[II]和芳香族羧酸[III-2]的缩聚反应，生产出一种热致性液晶聚酯。化合物[I-2]和[II]的量基本相等，化合物[III-2]的量不超过[I-2]的 20 倍（以摩尔计）。这样就可以生产出具有良好耐热性、流动性和均匀性的热致性液晶聚酯。
• METHOD FOR OXIDIZING AROMATIC COMPOUND HAVING ALKYL SUBSTITUENT, METHOD FOR PRODUCING AROMATIC ALDEHYDE COMPOUND AND METHOD FOR PRODUCING AROMATIC CARBOXYLIC ACID ESTER
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP1669340A1

  公开（公告）日：2006-06-14

  The present invention relates a method for oxidation of an aromatic compound having an alkyl substituent, including reacting the aromatic compound having an alkyl substituent with an oxygen molecule to oxidize the alkyl substituent into an aldehyde group in the presence of a catalyst containing Ag and/or Au, and, if necessary, any one or more kinds of group VIII elements, supported on a carrier. The oxidation method of the present invention allows the production of an aromatic aldehyde compound or an aromatic carboxylic acid ester via this aromatic aldehyde compound in high yield and in high selectivity by the use of a catalyst having moderate oxidizing ability, even when an aromatic compound having an alkyl substituent, which is easily converted into an aromatic carboxylic acid by oxidation, is used as a starting material.

  本发明涉及一种具有烷基取代基的芳香族化合物的氧化方法，包括使具有烷基取代基的芳香族化合物与氧分子反应，在含有Ag和/或Au的催化剂存在下将烷基取代基氧化成醛基，必要时还可将任何一种或多种VIII族元素支撑在载体上。本发明的氧化方法通过使用具有中等氧化能力的催化剂，可以高产率、高选择性地生产芳香醛化合物或芳香羧酸酯，即使使用具有烷基取代基的芳香化合物作为起始原料，该芳香化合物也很容易通过氧化转化为芳香羧酸。
• JPS59206334A
  申请人：——

  公开号：JPS59206334A

  公开（公告）日：1984-11-22
• Method for oxidation of aromatic compound having alkyl substituent, method for production of aromatic aldehyde compound, and method for production of aromatic carboxylic acid ester
  申请人：Hayashi Toshio

  公开号：US20070038000A1

  公开（公告）日：2007-02-15

  The present invention relates a method for oxidation of an aromatic compound having an alkyl substituent, including reacting the aromatic compound having an alkyl substituent with an oxygen molecule to oxidize the alkyl substituent into an aldehyde group in the presence of a catalyst containing Ag and/or Au, and, if necessary, any one or more kinds of group VIII elements, supported on a carrier. The oxidation method of the present invention allows the production of an aromatic aldehyde compound or an aromatic carboxylic acid ester via this aromatic aldehyde compound in high yield and in high selectivity by the use of a catalyst having moderate oxidizing ability, even when an aromatic compound having an alkyl substituent, which is easily converted into an aromatic carboxylic acid by oxidation, is used as a starting material.
• US5298593A
  申请人：——

  公开号：US5298593A

  公开（公告）日：1994-03-29