Trifluormethyyl-difluormethyl-fluoramin | 2106-99-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: Trifluormethyyl-difluormethyl-fluoramin
• 英文别名: N-(difluoromethyl)-N,1,1,1-tetrafluoromethanamine
• CAS: 2106-99-2
• 化学式: C₂HF₆N
• 分子量: 153.027
• InChiKey: SSPQPAVWMHMINY-UHFFFAOYSA-N

物化性质

• 沸点：
  -7.5 °C
• 密度：
  1.501±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  甲胺 在 fluorine 作用下， 生成 Trifluormethyyl-difluormethyl-fluoramin
  参考文献：
  名称：

  The Action of Elementary Fluorine upon Organic Compounds. XXIV. The Jet Fluorination of Hydrogen Cyanide, Cyanogen, Methylamine and Ethylenediamine. Pyrolysis and Fluorinolysis of Selected Products¹

  摘要：

  DOI：

  10.1021/ja01485a030

文献信息

• Electrochemical fluorination of N,N,N′,N′-tetramethylethylenediamine
  作者：P. Sartoria、D. Velayutham、N. Ignat'eva、M. Noel

  DOI：10.1016/s0022-1139(97)00002-x

  日期：1997.6

  The electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine was carried out in a modified Simons type cell using anhydrous hydrogen fluoride as a solvent. Effects of various experimental parameters like concentration of amine, temperature, and current density etc. were investigated. In addition to perfluoro-N,N,N',N'-tetramethylethylenediamine, cyclic, cleavage, and partially fluorinated products were obtained and characterized by gas chromatography, IR spectroscopy, nuclear magnetic resonance and mass spectra. A plausible reaction pathway for the electrochemical fluorination of N,N,N',N'-tetramethylethylenediamine has been proposed based on the products obtained. (C) Elsevier Science S.A.
• The Action of Elementary Fluorine upon Organic Compounds. XXIV. The Jet Fluorination of Hydrogen Cyanide, Cyanogen, Methylamine and Ethylenediamine. Pyrolysis and Fluorinolysis of Selected Products¹
  作者：Peter Robson、Victor C. R. McLoughlin、John B. Hynes、Lucius A. Bigelow

  DOI：10.1021/ja01485a030

  日期：1961.12