1,3-bis(2-hydroxyethyl)-5-methyl-1,3,5-triazine-2(1H),4(3H),6(5H)-trione | 420087-78-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,3-bis(2-hydroxyethyl)-5-methyl-1,3,5-triazine-2(1H),4(3H),6(5H)-trione
• 英文别名: 1-methyl-3,5-bis(ω-hydroxyethyl)isocyanurate；1-methyl 3,5-bis(2-hydroxyethyl) isocyanurate；1-Methyl 3,5-bis-(2-hydroxyethyl) isocyanurate；1,3-bis(2-hydroxyethyl)-5-methyl-1,3,5-triazinane-2,4,6-trione
• CAS: 420087-78-1
• 化学式: C₈H₁₃N₃O₅
• 分子量: 231.208
• InChiKey: QZLHYSQVUXEMFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2
• 重原子数：
  16
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  101
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,3-bis(2-hydroxyethyl)-5-methyl-1,3,5-triazine-2(1H),4(3H),6(5H)-trione 在 碘 、 对甲苯磺酸 、 三乙胺 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 反应 4.0h， 生成 3,5-bis(4,9-dioxo-3,10-dioxa-6,7-dithiadodeca-1,12-diyl)-1-methyl-1,3,5-triazine-2,4,6(1H,3H,5H)-trione
  参考文献：
  名称：

  Synthesis of 1-Alkyl 3,5-Bis( -mercaptoacetoalkyl) Isocyanurates and Macrocyclic Disulfides Derived Thereof

  摘要：

  1-Alkyl 3,5-bis(omega-hydroxyalkyl) isocyanurates were reacted with mercaptoacetic acid to obtain 3,5-bis(omega-mercaptoacetoxyalkyl) isocyanurates whose oxidation gives rise to macrocyclic disulfides.

  DOI：

  10.1023/b:rugc.0000007661.56422.a7
• 作为产物：
  描述：

  monomethylisocyanuric acid 、 2-氯乙醇 在 sodium 、 正丁醇 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以62%的产率得到1,3-bis(2-hydroxyethyl)-5-methyl-1,3,5-triazine-2(1H),4(3H),6(5H)-trione
  参考文献：
  名称：

  摘要：

  1-Methyl or 1-benzyl 3,5-bis(omega-bromoalkyl) isocyanurates with the alkyl chain comprising 3 through 6 methylene units were synthesized by the reaction of disodium methyl and benzyl isocyanurates with alpha,omega-dibromoalkanes. The reaction of disodium methyl and benzyl isocyanurates with ethylene chlorohydrin was used to obtain 1-methyl or 1-benzyl 3,5-bis(2-hydroxyethyl) isocyanurates whose treatment with PBr3 or SOCl2 gave the corresponding 1-alkyl 3,5-bis(2-haloethyl) isocyanurates. 1-Methyl and 1-benzyl 3,5-bis(chloromethyl) isocyanurates were prepared by treatment With SOCl2 of 1-methyl or 1-benzyl 3,5-bis(hydroxymethyl) isocyanurates obtained, in their turn, by condensation of methyl and benzyl isocyanurates with formaldehyde.

  DOI：

  10.1023/a:1013166023627

文献信息

• Methods of forming patterns using compositions for an underlayer of photoresist
  申请人：Samsung Electronics Co., Ltd.

  公开号：US10712662B2

  公开（公告）日：2020-07-14

  A method of forming a pattern is disclosed. The method includes preparing a composition that includes a solvent and a polymer including a repeating unit in which at least one isocyanurate unit having a first structure is connected to another isocyanurate unit having a second structure different from the first structure; applying the composition on a substrate to form an underlayer; forming a photoresist layer on the underlayer; etching the photoresist layer to form a photoresist pattern; and patterning the substrate using the photoresist pattern.

  本发明公开了一种形成图案的方法。该方法包括制备一种组合物，该组合物包括溶剂和聚合物，聚合物包括重复单元，其中至少一个具有第一结构的异氰脲酸酯单元与另一个具有不同于第一结构的第二结构的异氰脲酸酯单元相连接；将组合物涂在基底上以形成底层；在底层上形成光刻胶层；蚀刻光刻胶层以形成光刻胶图案；以及使用光刻胶图案对基底进行图案化。
• ——
  作者：S. G. Fattakhov、M. M. Shulaeva、V. S. Reznik

  DOI：10.1023/a:1013281230316

  日期：——

  Alkylation of disodium benzyl and disodium methyl isocyanurates with beta,beta'-dichlorodiethyl and beta,beta'-dibromodiethyl ethers was used to prepare 1-benzyl and 1-methyl 3,5-bis[2-(2-haloethoxy)ethyl] isocyanurates whose reaction with thiourea followed by hydrolysis gave the corresponding 1-alkyl 3,5-bis[2(2-mercaptoethoxy)ethyl] isocyanurates. 1-Benzyl and 1-methyl 3,5-bis[2-(2-chloroethyl)ethyl] isocyanurates were reacted with NaSCH2CH2OH to obtain the corresponding 1-alkyl 3,5-bis[2-(2-hydroxyethylthio)ethyl] isocyanurates. Treatment of the latter two esters with thionyl chloride gave 1-benzyl and 1-methyl 3,5-bis[2-(2-chloroethylthio)ethyl] isocyanurates, respectively.
• COATING COMPOSITION FOR PACKAGING ARTICLES
  申请人：SWIMC LLC

  公开号：EP3093320B1

  公开（公告）日：2021-07-21
• JP2011236175A
  申请人：——

  公开号：JP2011236175A

  公开（公告）日：2011-11-24
• Flowable Thermoplastic Materials With Halogen-Free Flame Protection
  申请人：Engelmann Jochen

  公开号：US20080194741A1

  公开（公告）日：2008-08-14

  Thermoplastic molding compositions, comprising A) from 10 to 98% by weight of at least one thermoplastic polymer, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate having an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of A x B y type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 1 to 40% by weight of a halogen-free flame retardant, selected from the group of the phosphorus-containing or nitrogen-containing compounds, or of the P—N condensates, or a mixture of these, D) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to D) is 100%.