disodium 4,4'-bis[(4-ethoxyphenyl)azo]stilbene-2,2'-disulfonate

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: disodium 4,4'-bis[(4-ethoxyphenyl)azo]stilbene-2,2'-disulfonate
• 英文别名: direct yellow 12；sodium;5-[(4-ethoxyphenyl)diazenyl]-2-[(E)-2-[4-[(4-ethoxyphenyl)diazenyl]-2-sulfonatophenyl]ethenyl]benzenesulfonate
• 化学式: C₃₀H₂₆N₄O₈S₂*2Na
• 分子量: 680.67
• InChiKey: UAWGEYZZCKAPHY-XBFRWELRSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  45
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  199
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  disodium 4,4'-bis[(4-ethoxyphenyl)azo]stilbene-2,2'-disulfonate 在 sodium tetrahydroborate 作用下， 生成 4,4'-diaminostilbene-2,2'-disulfonic acid disodium salt 、 对乙氧基苯胺
  参考文献：
  名称：

  Green synthesis of silver nanoparticles using Terminalia cuneata and its catalytic action in reduction of direct yellow-12 dye

  摘要：

  Facile green synthesis of silver nanoparticles (AgNPs) using aqueous bark extract of Terminalia cuneata has been reported in this article. The effects of concentration of the extract, reaction time and pH were studied by UV-Vis spectroscopy. Appearance of yellow color with lambda(max) around similar to 420 nm suggested the formation of AgNPs. The stable AgNPs were further characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) with zeta potential and high resolution transmission electron microscopy (HR-TEM) with energy dispersive X-ray spectroscopy (EDS) analysis. The synthesized AgNPs were in the size range of 25-50 nm with a distorted spherical shape identified from HR-TEM analysis. The catalytic activity of AgNPs on the reduction of direct yellow-12 using NaBH4 was analyzed using a UV-Vis spectrophotometer. This study showed the efficacy of biogenic AgNPs in catalyzing the reduction of direct yellow-12. (C) 2016 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2016.02.044

文献信息

• Green synthesis of silver nanoparticles using Terminalia cuneata and its catalytic action in reduction of direct yellow-12 dye
  作者：Thomas Nesakumar Jebakumar Immanuel Edison、Yong Rok Lee、Mathur Gopalakrishnan Sethuraman

  DOI：10.1016/j.saa.2016.02.044

  日期：2016.5

  Facile green synthesis of silver nanoparticles (AgNPs) using aqueous bark extract of Terminalia cuneata has been reported in this article. The effects of concentration of the extract, reaction time and pH were studied by UV-Vis spectroscopy. Appearance of yellow color with lambda(max) around similar to 420 nm suggested the formation of AgNPs. The stable AgNPs were further characterized by Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), dynamic light scattering (DLS) with zeta potential and high resolution transmission electron microscopy (HR-TEM) with energy dispersive X-ray spectroscopy (EDS) analysis. The synthesized AgNPs were in the size range of 25-50 nm with a distorted spherical shape identified from HR-TEM analysis. The catalytic activity of AgNPs on the reduction of direct yellow-12 using NaBH4 was analyzed using a UV-Vis spectrophotometer. This study showed the efficacy of biogenic AgNPs in catalyzing the reduction of direct yellow-12. (C) 2016 Elsevier B.V. All rights reserved.