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Y(OH)CO3 | 752947-76-5

中文名称
——
中文别名
——
英文名称
Y(OH)CO3
英文别名
Yttrium(3+);carbonate;hydroxide
Y(OH)CO<sub>3</sub>化学式
CAS
752947-76-5
化学式
CO3*HO*Y
mdl
——
分子量
165.922
InChiKey
CPGCPYVWUAXRKT-UHFFFAOYSA-K
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    -2.63
  • 重原子数:
    6
  • 可旋转键数:
    0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    64.2
  • 氢给体数:
    1
  • 氢受体数:
    4

反应信息

  • 作为反应物:
    描述:
    ammonium metavanadateY(OH)CO3 为溶剂, 反应 12.0h, 生成 yttrium(III) vanadate
    参考文献:
    名称:
    Hydrothermal synthesis of Y(V, P)O4:Ln3+ (Ln=Eu, Yb, and Er) with shape- and size-controlled morphologies
    摘要:
    DOI:
    10.1016/j.jallcom.2014.05.012
  • 作为产物:
    描述:
    yttrium(III) nitrate尿素 为溶剂, 反应 2.5h, 生成 Y(OH)CO3
    参考文献:
    名称:
    Up-conversion luminescence and near-infrared quantum cutting in Y6O5F8:RE3+ (RE = Yb, Er, and Ho) with controllable morphologies by hydrothermal synthesis
    摘要:
    通过简单的表面活性剂辅助水热路线构建了具有各种形貌的单分散均匀的 Y6O5F8:RE3+(RE = Yb、Er 和 Ho)微结构,并研究了它们的上转换发光和近红外量子切割特性。分别采用 CTAB、PVP 和 EDTA 作为添加剂设计了空心六角柱、棒状微束聚集和实心六角柱。在 980 nm 激发下,使用不同添加剂获得的 Y5.34O5F8:0.6Yb3+、0.06Er3+ 样品表现出相似的发射光谱曲线,主峰位于 670 nm; Y5.34O5F8:0.6Yb3+、0.06Ho3+ 样品发出绿光发射,最强峰值在 544 nm 附近。 Y6O5F8:Yb3+、Ho3+ 样品的近红外量子切割通过 360 和 450 nm 激发下的近红外发射光谱来确定。通过能级图讨论了相应的量子切割机制,其中首先提出了从Yb3+到Ho3+的反向能量转移来解释光谱特性。根据量子切割机制,提出了一种修正的450 nm激发耦合Yb3+-Ho3+量子效率的计算方程。 Yb3+、Ho3+ 共掺杂 Y6O5F8 的高效近红外发光和量子切割揭示了在改变太阳光谱以提高硅太阳能电池效率方面的可能应用。
    DOI:
    10.1039/c2dt32463f
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文献信息

  • Facile synthesis and color-tunable properties of monodisperse β-NaYF<sub>4</sub>:Ln<sup>3+</sup> (Ln = Eu, Tb, Tm, Sm, Ho) microtubes
    作者:Junfeng Yang、Lina Song、Xiaoxue Wang、Jianchao Dong、Shucai Gan、Lianchun Zou
    DOI:10.1039/c7dt04273f
    日期:——
    properties of β-NaYF4:Ln3+ (Ln = Eu, Tb, Tm, Sm, Ho) were studied in detail, and it was found that the photoluminescence color of β-NaYF4:0.03Tm3+ phosphor was close to the standard blue light (0.14, 0.08). Moreover, by co-doping the Tb3+ and Eu3+ ions into the β-NaYF4 host, multicolor tunable emissions were obtained due to the efficient energy transfer from Tb3+ to Eu3+ at 368 nm excitation. These merits
    在这项研究中,单分散和均匀的β-NaYF 4六角形微管成功地合成通过一个简单的水热法,没有任何有机表面活性剂,使用Y(OH)CO 3胶体球体作为前体。在一系列随时间变化的控制实验及其固有的晶体结构的基础上,研究了可能的形成机理。β-NaYF的积分发光强度4:0.05Tb 3+比α-NaYF强几乎1.78倍4:0.05Tb 3+。此外,光致发光特性β-NaYF 4:LN 3+(Ln为铕,铽,TM,SM,何)进行了研究详细地,并且发现β-NaYF的光致发光颜色4:0.03Tm 3+荧光体接近的标准蓝色光(0.14,0.08)。而且,通过共掺杂铽3+及Eu 3+离子进入β-NaYF 4主机,多色可调排放量由于从Tb中有效的能量转移获得3+与Eu 3+在368 nm激发。这些优点表明该材料可以在彩色显示领域中找到潜在的应用。
  • Evolution of Slow Magnetic Relaxation: from Diamagnetic Matrix Y(OH)CO<sub>3</sub> to Dy<sub>0.06</sub>Y<sub>0.94</sub>(OH)CO<sub>3</sub> with High Spin-Reversal Barrier and Blocking Temperature
    作者:Jiang Liu、Yan-Cong Chen、Jia-Jun Lai、Zi-Hao Wu、Long-Fei Wang、Quan-Wen Li、Guo-Zhang Huang、Jian-Hua Jia、Ming-Liang Tong
    DOI:10.1021/acs.inorgchem.6b00087
    日期:2016.3.21
    A stable DyIII-dispersed compound with single-molecule magnet behavior, Dy0.06Y0.94(OH)CO3, was isolated by a general strategy targeted at the doping of paramagnetic Dy3+ into a diamagnetic 3D inorganic network of Y(OH)CO3. The single-ion origin of slow magnetic relaxation was gradually released as variations of the dysprosium/yttrium ratio and finally gave a relatively large spin-reversal barrier
    通过针对顺磁性Dy 3+掺杂到Y(OH)的抗磁性3D无机网络中的一般策略,分离出具有单分子磁体行为的稳定的Dy III分散化合物Dy 0.06 Y 0.94(OH)CO 3。CO 3。缓慢磁弛豫的单离子起源随着as /钇比的变化而逐渐释放,并最终在200 K左右和8 K的高磁滞温度下产生了相对较大的自旋反转势垒。通过选择合适的具有强轴向各向异性的无机结构,可以降低磁弛豫和磁结构相关性。
  • AIKEN, BAR;HSU, WAN PETER;MATIJEVIC, EGON, J. MATER. SCI., 25,(1990) N, C. 1886-1894
    作者:AIKEN, BAR、HSU, WAN PETER、MATIJEVIC, EGON
    DOI:——
    日期:——
  • Hydrothermal synthesis of Y(V, P)O4:Ln3+ (Ln=Eu, Yb, and Er) with shape- and size-controlled morphologies
    作者:Jia Zhang、Zhangyin Zhai、Guibin Chen
    DOI:10.1016/j.jallcom.2014.05.012
    日期:2014.10
  • Up-conversion luminescence and near-infrared quantum cutting in Y6O5F8:RE3+ (RE = Yb, Er, and Ho) with controllable morphologies by hydrothermal synthesis
    作者:Jia Zhang、Yuhua Wang、Linna Guo、Pengyu Dong
    DOI:10.1039/c2dt32463f
    日期:——
    Monodisperse and uniform Y6O5F8:RE3+ (RE = Yb, Er, and Ho) microarchitectures with various morphologies have been constructed by a facile surfactant-assisted hydrothermal route, and their up-conversion luminescence and NIR quantum cutting properties were investigated. Hollow hexagonal prisms, microbundle gatherings by rods, and solid hexagonal prisms were designed by employing CTAB, PVP, and EDTA as additives, respectively. Under 980 nm excitation, the Y5.34O5F8:0.6Yb3+, 0.06Er3+ samples obtained using different additives exhibit similar emission spectra profiles with predominating peaks at 670 nm; the Y5.34O5F8:0.6Yb3+, 0.06Ho3+ samples give green emissions with the strongest peaks around 544 nm. The NIR quantum cutting for the Y6O5F8:Yb3+, Ho3+ samples was identified by the NIR emission spectra upon both 360 and 450 nm excitation. The corresponding quantum cutting mechanisms were discussed through the energy level diagrams, in which a back-energy-transfer from Yb3+ to Ho3+ was first proposed to interpret the spectral characteristics. A modified calculation equation for the quantum efficiency of Yb3+–Ho3+ coupled by exciting at 450 nm was suggested according to the quantum cutting mechanism. The efficient NIR luminescence and quantum cutting in Yb3+, Ho3+ co-doped Y6O5F8 reveal a possible application in modifying the solar spectrum to enhance the efficiency of silicon solar cells.
    通过简单的表面活性剂辅助水热路线构建了具有各种形貌的单分散均匀的 Y6O5F8:RE3+(RE = Yb、Er 和 Ho)微结构,并研究了它们的上转换发光和近红外量子切割特性。分别采用 CTAB、PVP 和 EDTA 作为添加剂设计了空心六角柱、棒状微束聚集和实心六角柱。在 980 nm 激发下,使用不同添加剂获得的 Y5.34O5F8:0.6Yb3+、0.06Er3+ 样品表现出相似的发射光谱曲线,主峰位于 670 nm; Y5.34O5F8:0.6Yb3+、0.06Ho3+ 样品发出绿光发射,最强峰值在 544 nm 附近。 Y6O5F8:Yb3+、Ho3+ 样品的近红外量子切割通过 360 和 450 nm 激发下的近红外发射光谱来确定。通过能级图讨论了相应的量子切割机制,其中首先提出了从Yb3+到Ho3+的反向能量转移来解释光谱特性。根据量子切割机制,提出了一种修正的450 nm激发耦合Yb3+-Ho3+量子效率的计算方程。 Yb3+、Ho3+ 共掺杂 Y6O5F8 的高效近红外发光和量子切割揭示了在改变太阳光谱以提高硅太阳能电池效率方面的可能应用。
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