1-NaphSbPh2 | 586356-93-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-NaphSbPh2
• CAS: 586356-93-6
• 化学式: C₂₂H₁₇Sb
• 分子量: 403.127
• InChiKey: VVNSFEPFUXLOTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.36
• 重原子数：
  23
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  diphenylfluorostibine 生成 1-NaphSbPh2
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.2.7, page 130 - 141

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sb: Org.Comp.1, 1.1.1.2.7, page 130 - 141
  作者：

  DOI：——

  日期：——
• Woods, L. A.; Gilman, H., Proceedings of the Iowa Academy of Science, 1941, vol. 48, p. 251
  作者：Woods, L. A.、Gilman, H.

  DOI：——

  日期：——
• Organoheteroatom Stannanes in Palladium-Catalyzed Cross-Coupling Reactions with 1-Naphthyl Triflate
  作者：Mariana Bonaterra、Roberto A. Rossi、Sandra E. Martín

  DOI：10.1021/om8009816

  日期：2009.2.9

  We have studied the Pd-catalyzed cross-coupling reaction of organoheteroatom stannanes containing elements of groups 15 (P, As, Sb) and 16 (Se) with 1-naphthyl triflate (3). The stannanes n-Bu(3)SnZPh(n) (Z = P, As, Sb, Se; n = 1, 2) were synthesized by the reaction of the Ph(n)Z(-) anion with n-Bu3SnCl. The cross-coupling reactions of these stannanes with 3 in a one-pot procedure afforded the C-heteroatom products Ph(n)Z-1-Naph in good yields for Z = As, Se (90 and 70% yields, respectively) and moderate yields for Z = P (51% yield). Only 18% of 1-naphthyldiphenylstibine was obtained. Optimization studies revealed that the combination of LiCl and free PPh3 ligand proved to be particularly effective in enhancing the coupling reaction.