O,O,O-tri(o,p-dimethylphenyl) phosphorothioate | 102962-93-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: O,O,O-tri(o,p-dimethylphenyl) phosphorothioate
• 英文别名: Tris(2,4-dimethylphenoxy)-sulfanylidene-lambda5-phosphane；tris(2,4-dimethylphenoxy)-sulfanylidene-λ5-phosphane
• CAS: 102962-93-6
• 化学式: C₂₄H₂₇O₃PS
• 分子量: 426.516
• InChiKey: JBIQPNAIPPIXSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.9
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  59.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,4-二甲基苯酚 在 PEG-400 sodium hydroxide 、 三氯氧磷 作用下， 以 氯仿 、 水 为溶剂， 反应 3.0h， 以82%的产率得到O,O,O-tri(o,p-dimethylphenyl) phosphorothioate
  参考文献：
  名称：

  Jadhav; Wadgaonkar; Salunkhe, Polish Journal of Chemistry, 1999, vol. 73, # 9, p. 1473 - 1475

  摘要：

  DOI：

文献信息

• Refrigerating Machine Oil, and Working Fluid Composition for Refrigerating Machine Which is Produced Using Same
  申请人：KH NEOCHEM CO., LTD.

  公开号：US20160168500A1

  公开（公告）日：2016-06-16

  Provided is a refrigerating machine oil which comprises an ester between a polyol consisting of at least one of pentaerythritol and dipentaerythritol represented by formula (I) and 2-propylheptanoic acid, and is characterized in that the refrigerating machine oil can be used in combination with a refrigerant consisting of 1,3,3,3-tetrafluoropropene (HFO-1234ze). When the refrigerating machine oil is used in combination with a refrigerant consisting of HFO-1234ze, excellent miscibility with the refrigerant, lubricity, thermal and chemical stability and the like can be achieved.

  提供的是一种制冷机油，其包括一种酯，该酯由式（I）表示的至少含有一种戊四醇和重聚戊四醇的多元醇和2-丙基庚酸之间的酯化反应形成，其特征在于该制冷机油可以与由1,3,3,3-四氟丙烯（HFO-1234ze）组成的制冷剂结合使用。当该制冷机油与由HFO-1234ze组成的制冷剂结合使用时，可以实现与制冷剂的良好相容性、润滑性、热和化学稳定性等。
• Flame retardant polyphenylene oxide thermoplastics
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0175281A2

  公开（公告）日：1986-03-26

  Flame retardant blends of polyphenylene oxide and styrene resin are provided as a result of the use of a minor amount of a triorganothiophosphate.

  由于使用了少量的三有机硫代磷酸酯，提供了聚苯醚和苯乙烯树脂的阻燃混合物。
• Flame retarding resin composition
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0612806A1

  公开（公告）日：1994-08-31

  A flame retarding resin composition comprising 100 parts by weight of a specific rubber-reinforced resin, 1-200 parts by weight of a phenol resin, 1-200 parts by weight of an organic phosphorus compound, 1-50 parts by weight of a nitrogen-containing compound, 0-40 parts by weight of an oligomer-type polymer containing a functional group, 0-30 parts by weight of a metal compound, a silicon compound, and/or polytetrafluoroethylene, and 0-300 parts by weight of a styrene-type resin. The composition has high impact resistance, excellent heat resistance, and a superior self-fire-extinguishing characteristic.

  一种阻燃树脂组合物，其成分包括 100 份（按重量计）特定橡胶增强树脂、1-200 份（按重量计）苯酚树脂、1-200 份（按重量计）有机磷化合物、1-50 份（按重量计）含氮化合物、0-40 份（按重量计）含有官能团的低聚物型聚合物、0-30 份（按重量计）金属化合物、硅化合物和/或聚四氟乙烯，以及 0-300 份（按重量计）苯乙烯型树脂。该组合物具有高抗冲击性、优异的耐热性和卓越的自熄火特性。
• Laser marking resin composition
  申请人：JAPAN SYNTHETIC RUBBER CO., LTD.

  公开号：EP0708147A1

  公开（公告）日：1996-04-24

  A laser marking resin composition excellent in appearance of molded article and impact resistance which comprises: (A) 100 parts by weight of a rubber-reinforced vinyl resin consisting of: (A-1) 1 to 100% by weight of a rubber-reinforced resin having a grafting degree of 5 to 150% by weight obtained by polymerizing, in the presence of (a) 5 to 70% by weight of a rubbery polymer, (b) 95 to 30% by weight of at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound, provided that (a) + (b) = 100% by weight, and (A-2) 99 to 0% by weight of a polymer obtained by polymerizing at least one monomer selected from the group consisting of an aromatic vinyl compound, a vinyl cyanide compound, a (meth)acrylic acid ester, maleic anhydride and a maleimide compound, provided that (A-1) + (A-2) = 100% by weight, the matrix resin in the component (A) having an intrinsic viscosity [η] of 0.1 to 1.5 dl/g as measured in methyl ethyl ketone at 30°C, and (B) 0.01 to 30 parts by weight of at least one compound selected from the group consisting of (B-1) titanium black, (B-2) black iron oxide, (B-3) yellow iron oxide and (B-4) carbon black.

  一种激光打标树脂组合物，具有优异的成型品外观和抗冲击性，包括 (A) 100 重量份的橡胶增强乙烯基树脂，由以下成分组成 (A-1)1-100%（按重量计）接枝度为 5-150%（按重量计）的橡胶增强树脂，该树脂是在(a)5-70%（按重量计）的橡胶聚合物，(b)95-30%（按重量计）的至少一种单体的存在下聚合而成，该单体选自由芳香族乙烯基化合物、乙烯基氰化物、（甲基）丙烯酸酯、马来酸酐和马来酰亚胺化合物组成的组，条件是(a)+(b)=100%（按重量计），以及 (A-2) 通过聚合至少一种选自芳香族乙烯基化合物、乙烯基氰化物、(甲基)丙烯酸酯、马来酸酐和马来酰亚胺化合物的单体而得到的聚合物，重量百分比为 99-0%、 以重量计，(A-1)+(A-2)=100%，组分(A)中的基体树脂在 30°C 的甲乙酮中的固有粘度[η]为 0.1 至 1.5 dl/g，以及 (B) 0.01 至 30 重量份的至少一种化合物，选自(B-1)钛黑、(B-2)黑氧化铁、 (B-3)黄氧化铁和(B-4)炭黑组成的组。
• Thermoplastic resin composition
  申请人：Techno Polymer Co., Ltd.

  公开号：EP0937747A2

  公开（公告）日：1999-08-25

  A thermoplastic resin composition comprises (A) 60 to 99 parts by weight of a thermoplastic resin obtainable by polymerizing 0 to 20% by weight of a monomer (b) containing at least one functional group selected from hydroxyl, epoxy, amino, carboxyl, acid anhydride, amide, imide and oxazoline groups, and not less than 10% and less than 100% by weight of at least one monomer (c) selected from aromatic vinyl compounds, vinyl cyanide compounds, acrylic esters, methacrylic esters and maleimide-based compounds, in the presence of more than 0% and not more than 70% by weight of a rubberlike polymer (a), the weight percentage being based on the total weight of (a), (b) and (c); and (B) 40 to 1 part by weight of a polyether ester amide obtainable by reacting 10 to 90% by weight of a polyamide (d), which is capped at the end of the molecule with a dicarboxylic acid (f) having not less than 21 and less than 60 carbon atoms, with 90 to 10% by weight of polyalkylene oxide (e), the weight percentage being based on the total weight of (d) and (e).

  一种热塑性树脂组合物包括(A)60 至 99 份(重量)的热塑性树脂，可通过聚合 0 至 20%(重量)的单体(b)获得，该单体(b)含有至少一个选自羟基、环氧基、氨基、羧基、酸酐、酰胺、亚胺和噁唑啉基团的官能团、以及不少于 10%但不超过 100%（按重量计）的至少一种单体（c），该单体选自芳香族乙烯基化合物、乙烯基氰化物、丙烯酸酯、甲基丙烯酸酯和马来酰亚胺基化合物，该单体存在于 0%以上但不超过 70%（按重量计）的橡胶状聚合物（a）中，该重量百分比基于（a）、（b）和（c）的总重量；(B) 40 至 1 份（按重量计）聚醚酯酰胺，可通过使 10 至 90%（按重量计）的聚酰胺 （d）与 90 至 10%（按重量计）的聚环氧烷（e）反应而获得，聚酰胺（d）在分子末端用 具有不少于 21 至 60 个碳原子的二羧酸（f）封端，重量百分比以（d）和（e）的总重 量为基准。