3-ethyl-3-[4-[(3-ethyloxtan-3-yl)methoxy]butoxymethyl]oxetane | 126050-33-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环丁烷
• 英文名称: 3-ethyl-3-[4-[(3-ethyloxtan-3-yl)methoxy]butoxymethyl]oxetane
• 英文别名: 3,3'-[Butane-1,4-diylbis(oxymethylene)]bis(3-ethyloxetane)；3-ethyl-3-[4-[(3-ethyloxetan-3-yl)methoxy]butoxymethyl]oxetane
• CAS: 126050-33-7
• 化学式: C₁₆H₃₀O₄
• 分子量: 286.412
• InChiKey: UWFHYGTWXNRUDH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  3-乙基-3-氧杂丁环甲醇 、 1,4-二氯丁烷 在 18-冠醚-6 、 sodium hydroxide 作用下， 以 水 为溶剂， 以81.9 %的产率得到3-ethyl-3-[4-[(3-ethyloxtan-3-yl)methoxy]butoxymethyl]oxetane
  参考文献：
  名称：

  US2023/116611

  摘要：

  公开号：

文献信息

• EPOXY-OXETANE COMPOUND, METHOD FOR SYNTHESIZING SAME, AND USE OF SAID COMPOUND
  申请人：SHIKOKU CHEMICALS CORPORATION

  公开号：US20200270236A1

  公开（公告）日：2020-08-27

  The purpose of the present invention is to provide: a novel curable compound which can be expected to be used as a raw material for photocurable resins and thermosetting resins; a method for synthesizing said compound; a resin composition containing said compound; and a cured product thereof. This compound is an epoxy-oxetane compound represented by a formula, and this compound has a structure in which two epoxycyclohexyl groups (groups in which an oxirane ring and a cyclohexane ring are condensed) are bonded to an oxetane ring via a connector having one ether bond. In formula (I′), R 1 to R 3 may be the same as, or different from, each other, and each denote a hydrogen atom or a methyl group. n is 1 or 2.

  本发明的目的是提供一种新型可固化化合物，可望用作光固化树脂和热固化树脂的原料；一种合成该化合物的方法；含有该化合物的树脂组合物；以及其固化产物。该化合物是一种由公式表示的环氧-氧杂环己烷化合物，该化合物具有两个环氧环己基团（氧环烷环与环己烷环结合）通过一个具有一个醚键的连接器连接到一个氧杂环己烷环的结构。在公式（I′）中，R1至R3可能相同，也可能不同，每个代表一个氢原子或一个甲基基团。n为1或2。
• NOVEL SULFONIC ACID DERIVATIVE COMPOUND AND NOVEL NAPHTHALIC ACID DERIVATIVE COMPOUND
  申请人：Murai Toshihiko

  公开号：US20120289697A1

  公开（公告）日：2012-11-15

  Disclosed are a novel sulfonic acid derivative compound and a novel naphthalic acid derivative compound with high solubility in organic solvents, good photosensitivity, and suitability as a photoacid generator and a polymerization initiator. The sulfonic acid derivative compound is represented by the formula (I) (wherein R 01 , R 04 , R 05 , and R 06 represent a hydrogen atom; any one of R 02 and R 03 represents an alkoxy group having a carbon number of 4 to 18 which may be substituted with an alicyclic hydrocarbon group, a heterocyclic group, or a halogen atom and which may have a branch, or the like; and R 07 represents an aliphatic hydrocarbon group having a carbon number of 1 to 18 which may be substituted with a halogen atom and/or an alkylthio group, or the like).

  揭示了一种新颖的磺酸衍生物化合物和一种新颖的萘甲酸衍生物化合物，具有在有机溶剂中高溶解度、良好的光敏性，并适用于光酸发生剂和聚合引发剂。磺酸衍生物化合物由以下式(I)表示（其中R01、R04、R05和R06代表氢原子；R02和R03中的任一表示具有4至18个碳原子的烷氧基，可以被取代为脂环烃基、杂环基或卤素原子，并且可以具有支链等；R07表示具有1至18个碳原子的脂肪烃基，可以被取代为卤素原子和/或烷基硫基等）。
• ONIUM SALT AND COMPOSITION COMPRISING THE SAME
  申请人：ASAHI KASEI E-MATERIALS CORPORATION

  公开号：US20160229801A1

  公开（公告）日：2016-08-11

  The onium salt of the present invention contains predetermined compound A represented by the general formula (1). The composition of the present invention contains the onium salt of the present invention, and an onium salt containing predetermined compound B represented by the general formula (2). The onium salt and the composition of the present invention exert well-balanced excellent physical properties in terms of cold curing properties, storage stability, thermal shock resistance after curing, and moisture resistance.

  本发明的季铵盐包含由通式（1）表示的预定化合物A。本发明的组合物包含本发明的季铵盐，以及由通式（2）表示的含有预定化合物B的季铵盐。本发明的季铵盐和组合物在冷固化性能、储存稳定性、固化后的耐热冲击性和耐湿性方面表现出良好的平衡优异物理性能。
• SULFONIUM SALT, PHOTOACID GENERATOR, AND PHOTOSENSITIVE COMPOSITION
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20170305848A1

  公开（公告）日：2017-10-26

  A novel sulfonium salt having high sensitivity with respect to active energy rays, a photoacid generator including the sulfonium salt, and a photosensitive composition containing the photoacid generator. The sulfonium salt is represented by formula (a1). In the formula, R 1 and R 2 each independently represent the group that is represented by formula (a2) or an alkyl group that may be substituted by a halogen atom, R 1 and R 2 are bonded to each other and may form a ring with the sulfur atom within the formula, R 3 is the group represented by formula (a3) or the group represented by formula (a4), A 1 represents S or the like, X − represents a monovalent anion, and R 1 and R 2 are not both an alkyl group which may be substituted with a halogen atom. In formulas (a2) to (a4), the ring Z 1 represents an aromatic hydrocarbon ring, R 4 , R 6 , R 9 , and R 10 each represents a specific monovalent group, R 5 , R 7 , and R 8 each represents a specific divalent group, A 2 and A 3 each represents S or the like, m1 represents an integer of 0 or more, and n1 and n2 each represent 0 or more.

  一种对活性能量射线具有高敏感度的新型磺鎓盐，包括该磺鎓盐的光酸发生剂以及含有该光酸发生剂的光敏组合物。该磺鎓盐由公式（a1）表示。在该公式中，R1和R2分别表示由公式（a2）表示的基团或可能被卤素原子取代的烷基基团，R1和R2彼此相连并且可以与公式中的硫原子形成环，R3表示由公式（a3）表示的基团或由公式（a4）表示的基团，A1表示S或类似物，X-表示一价阴离子，且R1和R2不同时为可能被卤素原子取代的烷基基团。在公式（a2）到（a4）中，环Z1表示芳香族碳氢环，R4、R6、R9和R10各自表示特定的一价基团，R5、R7和R8各自表示特定的二价基团，A2和A3各自表示S或类似物，m1表示0或更多的整数，n1和n2各自表示0或更多。
• Polymerizable Actinic Radiation Curable Composition, Polymerization Method, Actinic Radiation Curable Ink and Image Formation Method, and Ink Jet Recording Apparatus and Epoxy Compound
  申请人：Sasa Nobumasa

  公开号：US20080107821A1

  公开（公告）日：2008-05-08

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of —O—, —S—, —SO—, —SO 2 —, —CBr 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —; R 1 to R 18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合光致酸固化组合物，包括一种光酸发生化合物和一种由式（1）表示的环氧化合物：其中X代表从羟基、硫基、磺酸基、磺酸酯基、溴代基、三溴甲基代基和三氟甲基代基中选择的二价基团；R1至R18各自独立地表示氢原子、卤素原子、具有1-8个碳原子的碳氢基团，其中碳氢基团可能含有氧原子或卤素原子，或具有1-8个碳原子的取代或未取代的烷氧基团。