6-methacryloyloxy-naphthalene-2-carboxylic acid | 1184927-07-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-methacryloyloxy-naphthalene-2-carboxylic acid
• 英文别名: 6-(2-Methylprop-2-enoyloxy)naphthalene-2-carboxylic acid
• CAS: 1184927-07-8
• 化学式: C₁₅H₁₂O₄
• 分子量: 256.258
• InChiKey: DQKKPGXVVWDJFA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  triphenylsulfonium 1,1,3,3,3-pentafluoro-2-hydroxypropanesulfonate 、 草酰氯 、 6-methacryloyloxy-naphthalene-2-carboxylic acid 、 4-甲基-2-戊酮 在 盐酸 、 N,N-dimethylamino-pyridine 、 三乙胺 作用下， 以 二氯甲烷 、 甲苯 为溶剂， 以89%的产率得到triphenylsulfonium 1,1,3,3,3-pentafluoro-2-(6-methacryloyloxy-naphthalene-2-carbonyloxy)-propane-1-sulfonate
  参考文献：
  名称：

  POLYMERIZABLE ANION-CONTAINING SULFONIUM SALT AND POLYMER, RESIST COMPOSITION, AND PATTERNING PROCESS

  摘要：

  提供具有式（1）的可聚合含阴离子的亚砜盐，其中R1为H、F、甲基或三氟甲基，R2、R3和R4为C1-C10烷基、烯基或氧代烷基或C6-C18芳基、芳基烷基或芳氧代烷基，或R2、R3和R4中的两个可以结合在一起形成与S的环，A为C1-C10有机基团，n为0或1。该亚砜盐在暴露于高能辐射时生成非常强的磺酸。还提供了包含从该亚砜盐衍生的聚合物的抗蚀组合物。

  公开号：

  US20100055608A1

文献信息

• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY ELEMENT COMPRISING THE LIQUID CRYSTAL COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2243813A1

  公开（公告）日：2010-10-27

  A liquid crystal composition comprising 100 parts by mass of a nematic liquid crystal composition having negative dielectric anisotropy and 0.01 to 3 parts by mass of a polymerizable compound of general formula (I). On being irradiated with an energy ray, such as UV rays, the liquid crystal composition provides an LCD capable of high-speed response without undergoing reduction in reliability (voltage holding ratio). In formula (I), rings C1, C2, and C3 are each benzene, cyclohexane or naphthalene; M1 and M2 are each hydrogen or methyl; Z1 is a direct bond, -L1-, -L1O-, etc.; Z4 is a direct bond, -L2-, -OL2-, etc.; at least one of Z1 and Z4 is not a direct bond; L1 and L2 are each C1-C10 alkylene; when Z1=Z4, one or more hydrogen atoms of the rings C1, C2, and C3 are substituted; Z2 and Z3 are each a direct bond, an ester bond, etc.; p and q are each 0 or 1, provided that p+q≥1.

  一种液晶组合物，由 100 份（质量份）具有负介电各向异性的向列液晶组合物和 0.01 至 3 份（质量份）通式（I）的可聚合化合物组成。当受到能量射线（如紫外线）照射时，该液晶组合物可提供高速响应的液晶显示器，而不会降低可靠性（电压保持率）。 在式 (I) 中，环 C1、C2 和 C3 分别是苯、环己烷或萘；M1 和 M2 分别是氢或甲基；Z1 是直接键、-L1-、-L1O- 等；Z4 是直接键、-L2-、-OL2- 等。当 Z1=Z4 时，环 C1、C2 和 C3 的一个或多个氢原子被取代；Z2 和 Z3 各为直接键、酯键等；p 和 q 各为 0 或 1，条件是 p+q≥1。
• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND, AND LIQUID CRYSTAL DISPLAY DEVICE COMPRISING THE LIQUID CRYSTAL COMPOSITION
  申请人：Adeka Corporation

  公开号：EP2243813B1

  公开（公告）日：2015-11-04
• LIQUID CRYSTAL COMPOSITION CONTAINING POLYMERIZABLE COMPOUND AND LIQUID CRYSTAL DISPLAY USING THE LIQUID CRYSTAL COMPOSITION
  申请人：Matsumoto Ken

  公开号：US20100328601A1

  公开（公告）日：2010-12-30

  A liquid crystal composition includes 100 parts by mass of a nematic liquid crystal composition having negative dielectric anisotropy and 0.01 to 3 parts by mass of a polymerizable compound of general formula (I). On being irradiated with an energy ray, such as UV rays, the liquid crystal composition provides an LCD capable of high-speed response without undergoing reduction in reliability (voltage holding ratio). In formula (I), rings C 1-3 are benzene, cyclohexane or naphthalene; M 1-2 are hydrogen or methyl; Z 1 is a direct bond, -L 1 -, -L 1 O—, etc.; Z 4 is a direct bond, -L 2 -, —OL 2 -, etc.; at least one of Z 1 and Z 4 is not a direct bond; L 1,2 are C1-C10 alkylene; when Z 1 ═Z 4 , one or more hydrogen atoms of the rings C 1 , C 2 , and C 3 are substituted; Z 2 and Z 3 are each a direct bond, an ester bond, etc.; p and q are each 0 or 1, provided that p+q≧1.
• US8057985B2
  申请人：——

  公开号：US8057985B2

  公开（公告）日：2011-11-15
• US8283000B2
  申请人：——

  公开号：US8283000B2

  公开（公告）日：2012-10-09