4-Methyl-naphthalin-thiol-1 | 6383-53-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-Methyl-naphthalin-thiol-1
• 英文别名: 4-methyl-naphthalene-1-thiol；4-Methyl-thionaphthol-(1)；4-Mercapto-1-methyl-naphthalin；4-Methyl-naphthalin-1-thiol；4-Methylnaphthalene-1-thiol
• CAS: 6383-53-5
• 化学式: C₁₁H₁₀S
• 分子量: 174.266
• InChiKey: MNXLSODRJUQNRP-UHFFFAOYSA-N

物化性质

• 沸点：
  168-178 °C(Press: 25 Torr)
• 密度：
  1.143±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-Methyl-naphthalin-thiol-1 在 氨 作用下， 生成 bis-(4-methyl-[1]naphthyl)-disulfide
  参考文献：
  名称：

  Elbs; Christ, Journal fur praktische Chemie (Leipzig 1954), 1923, vol. <2> 106, p. 23

  摘要：

  DOI：
• 作为产物：
  描述：

  1-溴-4-甲基萘 生成 4-Methyl-naphthalin-thiol-1
  参考文献：
  名称：

  Cagniant,P.; Cagniant,D., Bulletin de la Societe Chimique de France, 1966, p. 2037 - 2042

  摘要：

  DOI：

文献信息

• [EN] NEW ORGANIC COMPOUNDS FOR ELECTROLUMINESCENCE AND ORGANIC ELECTROLUMINESCENT DEVICES USING THE SAME<br/>[FR] NOUVEAUX COMPOSES ORGANIQUES POUR L'ELECTROLUMINESCENCE ET DISPOSITIFS ELECTROLUMINESCENTS ORGANIQUES DANS LESQUELS ILS SONT UTILISES
  申请人：LG CHEMICAL LTD

  公开号：WO2003095445A1

  公开（公告）日：2003-11-20

  Disclosed is a novel group of compounds having a general structure of anthracene body substituted with at least one thiophenyl group, which can be further substituted with various substituent groups. These new compounds are generally compatible with organic electroluminescence. Also disclosed are organic electroluminescent devices and method of making the same. The organic electroluminescent devices include at least one of the compounds in various layers thereof. Organic electroluminescent devices employing the new compounds in their light-emitting layers show outstanding stability.

  揭示了一类新的化合物群，其具有一个蒽骨架的一般结构，并且至少被一种噻吩基团取代，该基团可以进一步被各种取代基团取代。这些新化合物通常与有机电致发光兼容。还揭示了有机电致发光器件以及其制备方法。有机电致发光器件包括其中的至少一种化合物在各种层中。在其发光层中使用新化合物的有机电致发光器件表现出出色的稳定性。
• Sulfhydryl-Directed Iridium-Catalyzed C–H/Diazo Coupling and Tandem Annulation of Naphthalene-1-thiols
  作者：Kelu Yan、Yong Kong、Bin Li、Baiquan Wang

  DOI：10.1021/acs.orglett.9b02581

  日期：2019.9.6

  The first sulfhydryl-directed iridium-catalyzed C-H/diazo coupling and tandem annulation of naphthalene-1-thiols has been developed. The framework of naphtho[1,8-bc]thiopyrans was constructed in a one-step reaction with good yields. This transformation provides a practical synthetic route for the widely used naphtho[1,8-bc]thiopyran derivatives.

  已经开发了第一巯基定向的铱催化的CH /重氮偶合和萘-1-硫醇的串联环化反应。萘并[1,8-bc]硫代吡喃的构架是一步反应构建的，产率很高。该转化为广泛使用的萘并[1,8-bc]硫代吡喃衍生物提供了实用的合成途径。
• Metal Thietane Compound, Polymerizable Composition Containing the Compound, Resin and Use of the Resin
  申请人：Murakami Masakazu

  公开号：US20130018169A1

  公开（公告）日：2013-01-17

  Polymerizable compositions containing at least one metal thietane compound represented by general formulas (110), (201) or (120), respectively, wherein said formulas are as follows: and wherein the identified moieties and n, p, q and r are defined.

  含有至少一种由通式（110）、（201）或（120）表示的金属噻吩化合物的聚合物组合物，其中所述的通式如下：其中所识别的基团和n、p、q和r已被定义。
• HIGHLY EFFICIENT CARBAZOLE-BASED COMPOUND, AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING SAME
  申请人：Lee Jun Yeob

  公开号：US20130119367A1

  公开（公告）日：2013-05-16

  The present invention relates to a highly efficient carbazole-based compound and to an organic electroluminescence device including the same. According to the present invention, provided are a compound for an organic electroluminescence device and an organic electroluminescence device including the compound, in which a carbazole-based phosphine oxide compound, which is a compound intended for an organic electroluminescence device, is employed to overcome the problems of conventional compounds for organic electroluminescence devices, i.e. those of instable thermal stability and low efficiency, and particularly, the compound of the present invention exhibits superior efficiency in pure-blue phosphorescent devices.

  本发明涉及一种高效的基于咔唑的化合物，以及包含该化合物的有机电致发光器件。根据本发明，提供了一种用于有机电致发光器件的化合物和包含该化合物的有机电致发光器件，其中采用了一种基于咔唑的膦氧化物化合物，该化合物旨在用于有机电致发光器件，以克服传统有机电致发光器件化合物的问题，即热稳定性不稳定和低效率，特别是本发明的化合物在纯蓝色磷光器件中表现出卓越的效率。
• METAL THIETANE COMPOUND, POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND, RESIN AND USE OF THE RESIN
  申请人：Murakami Masakazu

  公开号：US20100240862A1

  公开（公告）日：2010-09-23

  Disclosed is a metal thietane compound represented by the following general formula (120), (wherein, in the above general formula (120), M is a member selected from the group consisting of Bi, Sb, Ti, Zr and Ta; X 1 and X 2 are each independently a sulfur atom or an oxygen atom; R 1 is a divalent organic group; the bond between M and T shown by a dotted line and a solid line represents a single or double bond; m is an integer of 0 or 1 or more; n is the number of valence of M; and p is an integer of equal to or more than 1 and equal to or less than n, provided that when r is 1, q is 0 and Y is a monovalent inorganic or organic group; when r is 1 and n-p-q is 2 or more, a plurality of Ys contained are each independently selected from monovalent inorganic or organic groups; when r is 1 and n-p-q is 2 or more, a plurality of Ys may be bonded to each other to form a ring containing M; when r is 2, n-p-q is 1 or 2 and Y is a divalent group; when r is 2 and n-p-q is 2, two Ys may form a ring together with two Ms; and when r is 2 and q is 2, a plurality of Ts contained are each independently selected from inorganic or organic groups).

  公开了一种金属硫代环烷化合物，其通式如下（120），其中，在上述通式（120）中，M是从Bi、Sb、Ti、Zr和Ta组成的群体中选择的成员；X1和X2分别是硫原子或氧原子；R1是二价有机基团；M和T之间的键由虚线和实线表示，表示单键或双键；m是0或1或更多的整数；n是M的化合价数；p是大于或等于1且小于或等于n的整数，其中当r为1时，q为0且Y为一价无机或有机基团；当r为1且n-p-q为2或更多时，所含的多个Y各自独立地选择自一价无机或有机基团；当r为1且n-p-q为2或更多时，多个Y可以相互连接形成含M的环；当r为2时，n-p-q为1或2且Y为二价基团；当r为2且n-p-q为2时，两个Y可以与两个M一起形成环；当r为2且q为2时，所含的多个T各自独立地选择自无机或有机基团。