N,N-bis(2-azidoethyl)-4-[(4-nitrophenyl)diazenyl]aniline | 925694-43-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: N,N-bis(2-azidoethyl)-4-[(4-nitrophenyl)diazenyl]aniline
• CAS: 925694-43-5
• 化学式: C₁₆H₁₆N₁₀O₂
• 分子量: 380.369
• InChiKey: RSERIOWAEDBOEW-QURGRASLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.44
• 重原子数：
  28.0
• 可旋转键数：
  10.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  168.62
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  N,N-bis(2-azidoethyl)-4-[(4-nitrophenyl)diazenyl]aniline 在 三苯基膦 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 18.0h， 以211 mg的产率得到(E)-N1-(2-aminoethyl)-N1-(4-((4-nitrophenyl)diazenyl)phenyl)ethane-1,2-diamine
  参考文献：
  名称：

  Azobenzene coupled chromogenic receptors for the selective detection of copper(II) and its application as a chemosensor kit

  摘要：

  Azobenzene-based receptors 1-4 as colorimetric sensing materials were synthesized and their sensing properties were examined. In solution, the proposed sensing materials give rise to a large cation-induced hypochromic shift for Cu2+ resulting in a change from red to pale-yellow, whereas no significant color change was observed upon addition of other selected metal ions. The use of the silica gel plate modified with immobilization of receptor 4 to detect Cu2+ was also reported. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.11.066
• 作为产物：
  描述：

  N,N-bis(2-p-tolylsulfonyloxyethyl)aniline 在 sodium azide 、 硫酸 、 sodium nitrite 作用下， 以 水 、 溶剂黄146 、 二甲基亚砜 为溶剂， 反应 15.08h， 生成 N,N-bis(2-azidoethyl)-4-[(4-nitrophenyl)diazenyl]aniline
  参考文献：
  名称：

  Azobenzene coupled chromogenic receptors for the selective detection of copper(II) and its application as a chemosensor kit

  摘要：

  Azobenzene-based receptors 1-4 as colorimetric sensing materials were synthesized and their sensing properties were examined. In solution, the proposed sensing materials give rise to a large cation-induced hypochromic shift for Cu2+ resulting in a change from red to pale-yellow, whereas no significant color change was observed upon addition of other selected metal ions. The use of the silica gel plate modified with immobilization of receptor 4 to detect Cu2+ was also reported. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.11.066

文献信息

• Azobenzene coupled chromogenic receptors for the selective detection of copper(II) and its application as a chemosensor kit
  作者：Soo Jin Lee、Shim Sung Lee、Il Yun Jeong、Jin Yong Lee、Jong Hwa Jung

  DOI：10.1016/j.tetlet.2006.11.066

  日期：2007.1

  Azobenzene-based receptors 1-4 as colorimetric sensing materials were synthesized and their sensing properties were examined. In solution, the proposed sensing materials give rise to a large cation-induced hypochromic shift for Cu2+ resulting in a change from red to pale-yellow, whereas no significant color change was observed upon addition of other selected metal ions. The use of the silica gel plate modified with immobilization of receptor 4 to detect Cu2+ was also reported. (c) 2006 Elsevier Ltd. All rights reserved.