11-(4-decyloxyphenyl)benzofuro[3,2-b]carbazole | 1015076-93-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 11-(4-decyloxyphenyl)benzofuro[3,2-b]carbazole
• 英文别名: 11-(4-Decoxyphenyl)-[1]benzofuro[3,2-b]carbazole；11-(4-decoxyphenyl)-[1]benzofuro[3,2-b]carbazole
• CAS: 1015076-93-3
• 化学式: C₃₄H₃₅NO₂
• 分子量: 489.657
• InChiKey: KAKMYKXBZVKOTN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.2
• 重原子数：
  37
• 可旋转键数：
  11
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  27.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-碘癸烷 、 11-(4-hydroxyphenyl)benzofuro[3,2-b]carbazole 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 19.0h， 以50 mg的产率得到11-(4-decyloxyphenyl)benzofuro[3,2-b]carbazole
  参考文献：
  名称：

  Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing Both Pyrrole and Furan Rings

  摘要：

  Unsymmetrical heteroacenes, 11-phenylbenzofuro[3;2-b]carbazole (Ph-BFC) and its alkoxylated derivatives, were readily synthesized by palladium-catalyzed double N-arylation of arylamines. They characteristically form antiparallel cofacial pi-stacking arrangements, which may result from their unsymmetrical structures. Their physical properties show their potential for application as active layers in organic field-effect transistors.

  DOI：

  10.1021/ol703110g

文献信息

• Synthesis, Structures, and Properties of Unsymmetrical Heteroacenes Containing Both Pyrrole and Furan Rings
  作者：Keiko Kawaguchi、Koji Nakano、Kyoko Nozaki

  DOI：10.1021/ol703110g

  日期：2008.3.1

  Unsymmetrical heteroacenes, 11-phenylbenzofuro[3;2-b]carbazole (Ph-BFC) and its alkoxylated derivatives, were readily synthesized by palladium-catalyzed double N-arylation of arylamines. They characteristically form antiparallel cofacial pi-stacking arrangements, which may result from their unsymmetrical structures. Their physical properties show their potential for application as active layers in organic field-effect transistors.