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Tetrachlorotetrathiofulvalene | 121910-92-7

中文名称
——
中文别名
——
英文名称
Tetrachlorotetrathiofulvalene
英文别名
Tetrachlorotetrathiafulvalene;4,5-Dichloro-2-(4,5-dichloro-1,3-dithiol-2-ylidene)-1,3-dithiole
Tetrachlorotetrathiofulvalene化学式
CAS
121910-92-7
化学式
C6Cl4S4
mdl
——
分子量
342.142
InChiKey
YEOWNSQMJYAOOW-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    5.9
  • 重原子数:
    14
  • 可旋转键数:
    0
  • 环数:
    2.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    101
  • 氢给体数:
    0
  • 氢受体数:
    4

反应信息

点击查看最新优质反应信息

文献信息

  • Halogenation of Tetrathiafulvalene
    作者:Martin R. Bryce、Graeme Cooke
    DOI:10.1055/s-1991-26439
    日期:——
    Monolithiation of tetrathiafulvalene (2-(1,3-dithiol-2-ylidene)-1,3-dithiole, TTF) followed by reaction with the appropriate p-toluenesulphonyl halide yields monochloro-, monobromo- and monoiodo-TTF (34-48 % yield); tetrachloro-TTF is obtained in 30 % yield by tetralithiation of TTF followed by addition of p-toluenesulphonyl chloride. Cyclic voltammetric data establish that the oxidation potential of TTF is significantly increased upon halogenation.
    四硫富瓦烯(2-(1,3-二硫-2-亚烯基)-1,3-二硫烷,TTF)的单锂化反应后与适当的对甲苯磺酰卤反应,可以得到单氯、单溴和单碘- TTF(产率为34-48%);通过对TTF进行四锂化反应后,再加入对甲苯磺酰氯,可以获得四氯-TTF,产率为30%。循环伏安数据表明,TTF的氧化电位在卤素化后显著增加。
  • MULTISENSOR ARRAY FOR DETECTION OF ANALYTES OR MIXTURES THEREOF IN GAS OR LIQUID PHASE
    申请人:Jeppesen Jan Oskar
    公开号:US20130096030A1
    公开(公告)日:2013-04-18
    The present invention relates to a multisensor array for detection of analytes in the gas phase or in the liquid phase, comprising at least two different chemo-selective compounds represented by the general formula (I) wherein the hetero atoms X 1 -X 4 and the substituents R 1 -R 4 are defined in the specification and the dashed bonds represent independently of each other either a single bond or a double bond. Said chemo-selective compounds are capable of individually changing physicochemical properties when exposed to analytes or analyte mixtures and these changes can be detected by a transducer or an array of transducers. The present invention does also relate to the use of at least two different chemo-selective compounds in a sensor array, a method for preparation of such sensor arrays and the use of said sensor arrays. Furthermore the present invention relates to methods for detecting and identifying analytes or mixtures thereof in the gas phase or in the liquid phase.
    本发明涉及一种多传感器阵列,用于检测气相或液相中的分析物,包括至少两种不同的化学选择性化合物,由一般式(I)表示,其中杂原子X1-X4和取代基R1-R4在说明书中定义,虚线键独立地表示单键或双键。所述化学选择性化合物在暴露于分析物或分析物混合物时能够单独改变物理化学性质,这些变化可以被传感器或传感器阵列检测到。本发明还涉及在传感器阵列中使用至少两种不同的化学选择性化合物,制备这种传感器阵列的方法以及使用该传感器阵列的方法。此外,本发明还涉及检测和鉴定气相或液相中的分析物或混合物的方法。
  • JZHUSTORGENSEN, M.;VESNGAARD, K., SYNTHESIS (BRD),(1989) N, C. 207-208
    作者:JZHUSTORGENSEN, M.、VESNGAARD, K.
    DOI:——
    日期:——
  • US9671392B2
    申请人:——
    公开号:US9671392B2
    公开(公告)日:2017-06-06
  • Joergensen, M.; Bechgaard, K., Synthesis, 1989, # 3, p. 207 - 208
    作者:Joergensen, M.、Bechgaard, K.
    DOI:——
    日期:——
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同类化合物

四硫杂富瓦烯-D4 四硫富瓦烯 四(戊硫代)四硫富瓦烯 四(十八烷基硫代)四硫富瓦烯 四(乙硫基)四硫富瓦烯[有机电子材料] 双(亚乙基二硫醇)四硫代富瓦烯 双(三亚甲基二硫代)四硫富瓦烯 [1,3]二噻唑并[4,5-d]-1,3-二噻唑,2,5-二(1,3-二硫醇-2-亚基)- 5-甲基二硫杂环戊烯-3-硫酮 5-氨基-3-硫代氧基-3H-(1,2)二硫杂环戊烯-4-羧酸乙酯 5-氨基-3-硫代氧基-3H-(1,2)二硫杂环戊烯-4-甲腈 5,6-二氢-4H-环戊并[1,2]二硫代-3-硫酮 4,4’,5-三甲基四硫富瓦烯 4-甲基二硫杂环戊烯-3-硫酮 4-新戊基-3H-1,2-二硫杂环戊烯-3-硫酮 4,5-二甲基-3H-1,2-二硫醇-3-酮 4,5,6,7-四氢苯并[1,2]二硫-3-硫酮 4,4’-二甲基连四硫富瓦烯 4,4,5,5,6,6,7,7-八氢二苯并四硫富瓦烯 3H-1,2-二硫杂环戊二烯-3-酮 3H-1,2-二硫杂环戊二烯-3-硫酮 2-(4,5-二甲基-1,3-二硫杂环戊烯-2-亚基)-4,5-二甲基-1,3-二硫杂环戊烯 2,3,6,7-四(2-氰乙基硫代)四硫富瓦烯 1,3-二噻唑,2-[4,5-二(癸基硫代)-1,3-二硫醇-2-亚基]-4,5-二(癸基硫代)- (四甲基硫)四硫富瓦烯 2,3,6,7-tetrakis[2-(2-methoxyethoxy)ethylsulfanyl]tetrathiafulvalene 2,3-bis[2-(2-methoxyethoxy)ethylsulfanyl]-6,7-bis(methylsulfanyl)tetrathiafulvalene (5S,6S,5'S,6'S)-5,5',6,6'-tetramethyl-bis(ethylenedithio)tetrathiafulvalene 2,5-bis(4,5-ethylenedithio-1,3-dithiol-2-ylidene)-1,3,4,6-tetrathiapentalene 2,3,6,7-Tetrakis(1-octyloxymethyl)tetrathiafulvalene 2,3,6,7-Tetrakis(1-dodecyloxymethyl)tetrathiafulvalene 2,3,6,7-Tetrakis(1-pentyloxymethyl)tetrathiafulvalene 2,3,6,7-Tetrakis(1-hexyloxymethyl)tetrathiafulvalene 2,3,6,7-Tetrakis(1-propoxymethyl)tetrathiafulvalene 2,3,6,7-Tetrakis(1-decyloxymethyl)tetrathiafulvalene 2,3,6,7-Tetrakis(1-heptyloxymethyl)tetrathiafulvalene 2,6-bis(thioacetopentadecylamido)-3,7-bis(methylthiotetrathiafulvalene) 2,7-bis(thioacetopentadecylamido)-3,6-bis(methylthiotetrathiafulvalene) ethane 1,2-dithiol 2,3,6,7-Tetrakis(1-tetradecyloxymethyl)tetrathiafulvalene 2-Isopropyliden-1,3-dithiol-4,5-dicarbonitril 4,5-bis(butylthio)tetrathiafulvalene 2,3-dicyano-6,7-bis(butylthio)tetrathiafulvalene Tetrabutylammonium-(3-thioxo-3H-1,2-dithiol-5-thiolat) 5,6-dihydro-5-dimethoxymethyl-2-(5',6'-dihydro-1,3-dithiolo[4,5-b]-1,4-dithiin-2'-ylidene)-1,3-dithiolo[4,5-b]-1,4-dithiin 3H-1,2-dithiole 2,2'-(But-2-en-1,4-diyliden)bis[1,3-dithiol-4,5-dicarbonitril] 3-methylsulfanyl-[1,2]dithiolylium; iodide 2,2'-(Dodeca-2,4,6,8,10-pentaen-1,12-diyliden)bis[1,3-dithiol-4,5-dicarbonitril] (E,E)-1,6-bis[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]hexa-2,4-diene