trifluorovinyltriethoxysilane | 2925-45-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: trifluorovinyltriethoxysilane
• 英文别名: Trifluorovinyl triethoxysilane；triethoxy(1,2,2-trifluoroethenyl)silane
• CAS: 2925-45-3
• 化学式: C₈H₁₅F₃O₃Si
• 分子量: 244.286
• InChiKey: YEMSALKQGSGSMP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.65
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  硅酸四乙酯 、 三氟乙烯基溴化镁 以 四氢呋喃 为溶剂， 以8%的产率得到trifluorovinyltriethoxysilane
  参考文献：
  名称：

  Seyferth, D.; Wada, T.; Maciel, G. A., Inorganic Chemistry, 1962, vol. 1, p. 232 - 235

  摘要：

  DOI：
• 作为试剂：
  描述：

  三氟氯乙烯 、 仲丁基锂 、 硅酸四乙酯 在 乙醚 、 氩 、 trifluorovinyltriethoxysilane 作用下， 以 乙醚 为溶剂， 反应 3.25h， 以to result crude trifluorovinyltriethoxysilane, CF2═CFSi(OEt)3的产率得到trifluorovinyltriethoxysilane
  参考文献：
  名称：

  Hydrophobic materials for waveguides, optical devices, and other applications

  摘要：

  本发明揭示了波导（以及其他器件和材料，包括但不限于疏水涂层、钝化材料、球形封装材料、下填充材料、用于IC和其他应用的介电材料、微透镜和各种光学器件），这些器件和材料具有高度的疏水性和高度的稳定性，并且在其他方面也有益处。在本发明的一种实施例中，制造波导的方法包括：在基板上形成下包层；在下包层后形成芯层；在芯层后形成上包层；其中，下包层、芯层和/或上包层是疏水的，并且如果暴露在水中，则会产生90度或更高的水接触角。

  公开号：

  US07062145B2

文献信息

• Methods and compounds for making coatings, waveguides and other optical devices
  申请人：——

  公开号：US20030171607A1

  公开（公告）日：2003-09-11

  A compound of the general formula R 1 MR 4 R 5 R 6 is provided where R 1 is a partially or fully fluorinated aryl, alkyl, alkenyl or alkynyl group, wherein M is selected from group 14 of the periodic table, wherein R 4 , R 5 and R 6 are independently an alkoxy group OR 3 or a halogen group X—except, a) where R 4 , R 5 and R 6 are each ethoxy, M is Si and R 1 is perfluorinated phenyl or perfluorinated vinyl; b) where R 4 is ethoxy, R 5 and R 6 are chlorine, M is Si, and R 1 is perfluorinated phenyl; or c) where R 4 , R 5 and R 6 are chlorine, M is Si, and R 1 is perfluorinated phenyl, perfluorinated methyl or perfluorinated vinyl. This compound formed can be further reacted to attach an additional organic R group, and/or hydrolyzed, alone or with one or more similar compounds, to form a material having a molecular weight of from 500 to 10,000, which material can be deposited on various substrates as a coating or deposited and patterned for a waveguide or other optical device components. Methods for making compounds of the general formula R 1 MR 4 R 5 R 6 are also disclosed.

  提供了一种一般式为R1MR4R5R6的化合物，其中R1是部分或完全氟化的芳基、烷基、烯基或炔基，M选自周期表的14族，其中R4、R5和R6分别是烷氧基OR3或卤素基X-，但是：a)当R4、R5和R6均为乙氧基时，M为Si，R1为全氟苯基或全氟乙烯基；b)当R4为乙氧基，R5和R6为氯时，M为Si，R1为全氟苯基；或c)当R4、R5和R6均为氯时，M为Si，R1为全氟苯基、全氟甲基或全氟乙烯基。可以进一步反应该化合物以连接一个额外的有机R基团，并/或水解，单独或与一个或多个类似化合物一起形成分子量为500至10,000的材料，该材料可以沉积在各种基底上作为涂层或沉积和图案化为波导或其他光学器件组件。还公开了制备一般式为R1MR4R5R6的化合物的方法。
• Adhesion promoter and wetting agent
  申请人：——

  公开号：US20040115341A1

  公开（公告）日：2004-06-17

  An adhesion promoter for adhering a coating of a polymer, metal, metal oxide or fluorinated derivative thereof to an electrical or opto-electronic surface. The adhesion promoter is a hybrid organic-inorganic material which, in a preferred embodiment, includes silicon in the inorganic material.

  一种黏附促进剂，用于将聚合物、金属、金属氧化物或其氟化衍生物的涂层粘附到电气或光电表面上。该黏附促进剂是一种有机-无机杂化材料，其中在优选实施例中，无机材料中包括硅。
• Materials and methods for forming hybrid organic-inorganic dielectric materials for integrated circuit applications
  申请人：Rantala T. Juha

  公开号：US20060131753A1

  公开（公告）日：2006-06-22

  An integrated circuit is provided comprising a substrate and discrete areas of electrically insulating and electrically conductive material, wherein the electrically insulating material is a hybrid organic-inorganic material that has a density of 1.45 g/cm 3 or more and a dielectric constant of 3.0 or less. The integrated circuit can be made by a method comprising: providing a substrate; forming discrete areas of electrically insulating and electrically conductive material on the substrate; wherein the electrically insulating material is deposited on the substrate followed by heating at a temperature of 350° C. or less; and wherein the electrically insulating material is a hybrid organic-inorganic material that has a density of 1.45 g/cm 3 or more after densification. Also disclosed is a a method for making an integrated circuit comprising performing a dual damascene method with an electrically conductive material and a dielectric, the dielectric being a directly photopatterned hybrid organic-inorganic material.

  提供了一种集成电路，包括基底和电气绝缘和电气导体材料的离散区域，其中电气绝缘材料是一种混合有机-无机材料，具有1.45克/厘米3或更高的密度和3.0或更低的介电常数。该集成电路可以通过以下方法制造：提供基底；在基底上形成电气绝缘和电气导体材料的离散区域；其中电气绝缘材料在基底上沉积后，在350℃或更低的温度下加热；并且在致密化后，电气绝缘材料具有1.45克/厘米3或更高的密度。还公开了一种制造集成电路的方法，包括使用电气导体材料和介电材料执行双刻蚀法，其中介电材料是直接光图案化的混合有机-无机材料。
• Hybrid organic -inorganic materials for waveguides, optical devices, and other applications
  申请人：——

  公开号：US20030235933A1

  公开（公告）日：2003-12-25

  Waveguides are disclosed (and other devices and materials including but not limited to hybrid organic-inorganic coatings, passivation materials, glob top materials, underfill materials, materials for IC and other applications, microlenses and any of a wide variety of optical devices) that benefit by being formed of a novel hybrid organic-inorganic material. In one embodiment of the invention, a method for making a waveguide includes: forming a lower cladding layer on a substrate; forming a core layer after the lower cladding layer; and forming an upper cladding layer after the core layer; wherein the lower cladding layer, core layer and/or upper cladding layer comprises a hybrid organic-inorganic material—that has many desirable properties relating to stability, hydrophobicity, roughness, optical absorbance, polarization dependent loss, among others.

  本发明公开了波导（以及其他设备和材料，包括但不限于混合有机-无机涂层、钝化材料、球形封装材料、填充材料、用于集成电路和其他应用的材料、微透镜和各种光学设备），这些设备和材料由新型混合有机-无机材料构成，因此具有许多有益特性。在本发明的一种实施方案中，制造波导的方法包括：在基板上形成下部包层；在下部包层之后形成芯层；在芯层之后形成上部包层；其中下部包层、芯层和/或上部包层包含具有许多有益特性的混合有机-无机材料，这些特性包括稳定性、疏水性、粗糙度、光学吸收、偏振依赖损耗等。
• Materials having low optical loss for waveguides and other optical devices
  申请人：——

  公开号：US20040005131A1

  公开（公告）日：2004-01-08

  Waveguides and other devices and materials (including but not limited to waveguides, microlenses, and other optical device components), both planer and freespace devices benefit by having a high transparency or low optical loss profile at particular wavelengths. A method for making a waveguide comprises forming a lower cladding layer on a substrate; forming a core layer after the lower cladding layer, and forming an upper cladding layer after the core layer; wherein the lower cladding layer, core layer and/or upper cladding layer comprises a material having an optical loss of 0.1 dB/cm or less at 1550 nm, 1310 nm, C Band and/or L Band. The material having low optical loss also has other desirable properties in the areas of ease and temperature of deposition, hydrophobicity, direct patternability (photosensitivity), stress, aspect ratio if patterned, and surface and sidewall roughness (if patterned), among other characteristics.

  波导和其他器件和材料（包括但不限于波导、微透镜和其他光学器件组件），无论是平面还是自由空间设备，都受益于在特定波长下具有高透明度或低光学损耗特性。制作波导的方法包括在基底上形成下层包层；在下层包层之后形成芯层，并在芯层之后形成上层包层；其中下层包层、芯层和/或上层包层包含在1550nm、1310nm、C波段和/或L波段下具有0.1 dB/cm或更低光学损耗的材料。具有低光学损耗的材料还具有易于沉积和温度、疏水性、直接图案化（光敏性）、应力、图案化的纵横比和表面和侧壁粗糙度（如果图案化）等其他有利特性。