1,1,1,5,5-pentamethyl-5-phenyl-3,3-bis(trimethylsiloxy)trisiloxane | 1016636-32-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,1,1,5,5-pentamethyl-5-phenyl-3,3-bis(trimethylsiloxy)trisiloxane
• 英文别名: [Dimethyl(phenyl)silyl] tris(trimethylsilyl) silicate；[dimethyl(phenyl)silyl] tris(trimethylsilyl) silicate
• CAS: 1016636-32-0
• 化学式: C₁₇H₃₈O₄Si₅
• 分子量: 446.914
• InChiKey: DDOYMLXZESVEDN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.11
• 重原子数：
  26
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.65
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三(三甲基硅基氧化)硅醇 、 二甲基苯基乙烯基硅烷 在 氯化(双三环己基膦)(一氧化碳)(氢)钌 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以69%的产率得到1,1,1,5,5-pentamethyl-5-phenyl-3,3-bis(trimethylsiloxy)trisiloxane
  参考文献：
  名称：

  Silylation of silanols with vinylsilanes catalyzed by a ruthenium complex

  摘要：

  A new ruthenium complex-catalyzed O-silylation of silanols with vinylsilanes leading to siloxane bond formation with the evolution of ethylene is described. A maximum conversion of silanol is reached using an excess of vinylsilane to also yield the product of the homo-coupling of the latter. Under the optimum conditions, when vinylsilane with at least one ethoxy substituent is used, the reaction gives exclusively unsymmetrical siloxanes. (c) 2007 Published by Elsevier Ltd.

  DOI：

  10.1016/j.tetlet.2007.12.091

文献信息

• Silylation of silanols with vinylsilanes catalyzed by a ruthenium complex
  作者：Bogdan Marciniec、Piotr Pawluć、Grzegorz Hreczycho、Anna Macina、Martyna Madalska

  DOI：10.1016/j.tetlet.2007.12.091

  日期：2008.2

  A new ruthenium complex-catalyzed O-silylation of silanols with vinylsilanes leading to siloxane bond formation with the evolution of ethylene is described. A maximum conversion of silanol is reached using an excess of vinylsilane to also yield the product of the homo-coupling of the latter. Under the optimum conditions, when vinylsilane with at least one ethoxy substituent is used, the reaction gives exclusively unsymmetrical siloxanes. (c) 2007 Published by Elsevier Ltd.