trans-1,2-Dichlorcyclohexan | 72690-91-6

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: trans-1,2-Dichlorcyclohexan
• 英文别名: Cyclohexane, 1,2-dichloro-, trans-；(1S,2S)-1,2-dichlorocyclohexane
• CAS: 72690-91-6
• 化学式: C₆H₁₀Cl₂
• 分子量: 153.051
• InChiKey: GZEZIBFVJYNETN-WDSKDSINSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

文献信息

• Method for producing organic compounds by substituting halogen atoms
  申请人：MITSUI CHEMICALS, INC.

  公开号：EP1486479A1

  公开（公告）日：2004-12-15

  The invention pertains to a method in which a halogen atom of an organic compound is replaced with a group derived from a nucleophilic agent, at high yield and high efficiency, by the following method which includes a step of reacting the nucleophilic agent with an organic material having a halogen atom bonded to a carbon atom having four σ bonds, more specifically: a method for producing an organic compound having Q, the method including a step of reacting a compound represented by general formula (2) with an organic starting material having at least one halogen atom bonded to a carbon atom having four σ bonds so as to replace the halogen atom in the organic starting material with Q:         MQa     (2) (wherein M represents an alkali metal atom, an alkali earth metal atom, or a rare earth metal atom; Q represents a moiety of an inorganic acid or an active hydrogen compound derived by eliminating a proton, wherein Q is a halogen atom different from the halogen atom in the organic starting material having the halogen atom bonded to the carbon atom having the four σ bonds; and a represents an integer of 1 to 3) in the presence of a compound represented by general formula (1) (wherein Z- represents an anion derived by eliminating a proton from an inorganic acid or an active hydrogen compound; R2 is the same or different; R2 each independently represent a C1-C10 hydrocarbon group or two R2 on the same nitrogen atom may be bonded with each other to form a ring with the nitrogen atom).

  这项发明涉及一种方法，其中有机化合物中的卤素原子被来自亲核试剂的基团取代，且产率高效率高，通过以下方法实现，包括以下步骤：将亲核试剂与具有与碳原子形成四个σ键的卤素原子相结合的有机材料反应的步骤，更具体地说：一种用于生产具有Q的有机化合物的方法，包括以下步骤：将由通式（2）表示的化合物与至少一个卤素原子与碳原子形成四个σ键的有机起始材料反应，以将有机起始材料中的卤素原子替换为Q：         MQa     (2) （其中M代表碱金属原子、碱土金属原子或稀土金属原子；Q代表由消除质子衍生的无机酸或活性氢化合物的基团，其中Q是不同于有机起始材料中卤素原子的卤素原子，该卤素原子与具有四个σ键的碳原子相结合；a表示1到3的整数），在通式（1）表示的化合物的存在下 （其中Z-代表由无机酸或活性氢化合物中消除质子衍生的阴离子；R2相同或不同；R2各自独立地表示C1-C10烃基，或者两个R2在同一氮原子上可能与彼此结合形成与氮原子的环）。
• Diimines and secondary diamines
  申请人：Lee Y. John

  公开号：US20060217567A1

  公开（公告）日：2006-09-28

  This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

  这项发明提供了具有至少两个碳原子的亚烷基亚胺基团的芳香二亚胺和具有至少两个碳原子的氨基亚烷基团的芳香二胺。这些芳香二亚胺和芳香二胺可以是一个苯环的形式，也可以是由烷基桥连接的两个苯环的形式；每个邻位对着亚烷基基团或氨基基团。当以一个苯环的形式时，环上有两个亚胺基团或两个氨基团；亚胺基团或氨基团互为间位或对位。当以由烷基桥连接的两个苯环的形式时，每个苯环上要么有一个亚胺基团，要么有一个氨基基团。还提供了形成二亚胺和二胺的方法。
• Process for producing tetrakis(Faryl)borate salts
  申请人：——

  公开号：US20040068134A1

  公开（公告）日：2004-04-08

  The liquid ethereal medium or liquid hydrocarbyl medium of a solution or slurry of an alkali metal tetrakis( F aryl)borate is substituted with at least one halogenated hydrocarbon, without isolating the alkali metal tetrakis( F aryl)borate, to form a new slurry or solution. At least a portion of the new solution is mixed together with a salt selected from a) a protic ammonium salt, b) an onium salt, and c) a triarylmethyl salt, to produce a protic ammonium tetrakis( F aryl)borate, an onium tetrakis( F aryl)borate, or a triarylmethyl tetrakis( F aryl)borate.

  将含有碱金属四(芳基)硼酸盐的溶液或浆料中的液体乙醚介质或液体烃基介质用至少一种卤代烃代替，而无需分离碱金属四(芳基)硼酸盐，形成新的浆料或溶液。将新溶液的至少一部分与选择自a) 一种质子铵盐、b) 一种烷盐和c) 三芳基甲基盐的盐混合在一起，以生成一个质子铵四(芳基)硼酸盐、一个烷四(芳基)硼酸盐或一个三芳基甲基四(芳基)硼酸盐。
• DIIMINES AND SECONDARY DIAMINES
  申请人：Lee Y. John

  公开号：US20080033210A1

  公开（公告）日：2008-02-07

  This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

  本发明提供了具有至少两个碳原子的亚胺烃基亚胺基的芳香族二亚胺和具有至少两个碳原子的氨基烃基氨基的芳香族二级二胺。芳香族二亚胺和芳香族二级二胺均为一个苯环的形式或由一个烷基桥连接的两个苯环的形式；每个对位于亚胺基或氨基的位置都带有一个烃基基团。当为一个苯环的形式时，环上有两个亚胺基或两个氨基；亚胺基或氨基相对于彼此是间位或对位的。当为由一个烷基桥连接的两个苯环的形式时，每个苯环上有一个亚胺基或一个氨基。还提供了形成二亚胺和二级二胺的方法。
• Diimines and Secondary Diamines
  申请人：Lee John Y.

  公开号：US20080194788A1

  公开（公告）日：2008-08-14

  This invention provides aromatic diimines where the diimines have imino groups with at least two carbon atoms, and either are in the form of one benzene ring having two imino groups on the ring, which imino groups are meta or para relative to each other, and in which each position ortho to an imino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one imino group on each ring, and in which each position ortho to an imino group bears a hydrocarbyl group. This invention also provides aromatic secondary diamines where the diamines have amino hydrocarbyl groups with at least two carbon atoms, and either are in the form of one benzene ring having two amino groups on the ring, which amino groups are meta or para relative to each other, and in which each position ortho to an amino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one amino group on each ring, and in which each position ortho to an amino group bears a hydrocarbyl group. Also provided are processes for forming diimines and secondary diamines from primary diamines, including the aromatic diimines and aromatic secondary diamines of the invention.

  本发明提供了芳香二亚胺，其中二亚胺具有至少两个碳原子的亚胺基，并且可以是具有一个苯环的形式，在该苯环上具有两个亚胺基，这些亚胺基互为间位或对位，并且在每个与亚胺基相邻的位置上带有一个烃基团，或者是由一个烷基桥连接的两个苯环的形式，并且在每个与亚胺基相邻的位置上带有一个烃基团。本发明还提供了芳香二级二胺，其中二胺具有至少两个碳原子的氨基烃基团，并且可以是具有一个苯环的形式，在该苯环上具有两个氨基团，这些氨基团互为间位或对位，并且在每个与氨基团相邻的位置上带有一个烃基团，或者是由一个烷基桥连接的两个苯环的形式，并且在每个与氨基团相邻的位置上带有一个烃基团。本发明还提供了从一级二胺制备二亚胺和二级二胺的方法，包括本发明的芳香二亚胺和芳香二级二胺。