3-(2-carboxy-phenyl)-[2]naphthoic acid | 4860-29-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-(2-carboxy-phenyl)-[2]naphthoic acid
• 英文别名: 3-(2-Carboxy-phenyl)-[2]naphthoesaeure；3-(2-Carboxy-phenyl)-naphthalin-carbonsaeure-(2)；2-[3-Carboxy-naphthyl]-(2)]-benzoesaeure；3--naphthoesaeure-(2)；3-(2-Carboxy-phenyl)-naphthoesaeure-2；4,5-Benzdiphensaeure；3-(2-Carboxyphenyl)-2-naphthoic acid；3-(2-carboxyphenyl)naphthalene-2-carboxylic acid
• CAS: 4860-29-1
• 化学式: C₁₈H₁₂O₄
• 分子量: 292.291
• InChiKey: HPPMPFCULTWDSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-(2-carboxy-phenyl)-[2]naphthoic acid 在 硫酸 作用下， 生成 11-oxo-11H-benzo[a]fluorene-6-carboxylic acid
  参考文献：
  名称：

  Fieser; Dietz, Journal of the American Chemical Society, 1929, vol. 51, p. 3144

  摘要：

  DOI：
• 作为产物：
  描述：

  苯并[a]蒽 在 臭氧 作用下， 生成 3-(2-carboxy-phenyl)-[2]naphthoic acid
  参考文献：
  名称：

  Copeland et al., Chemistry and industry, 1959, p. 329

  摘要：

  DOI：

文献信息

• Studies in the Wagner Rearrangement.^1,2,3 II. The Synthesis and Structure Determination of Benz[a]anthracene-5,6-C₁¹⁴
  作者：Clair J. Collins、John G. Burr、Daniel N. Hess

  DOI：10.1021/ja01155a050

  日期：1951.11
• 12. Catalysed hydrogen peroxide oxidation of aromatic hydrocarbons. Part I
  作者：J. W. Cook、R. Schoental

  DOI：10.1039/jr9500000047

  日期：——
• SILICA ENCAPSULATED BIOMATERIALS
  申请人：Wackett Lawrence P.

  公开号：US20140051144A1

  公开（公告）日：2014-02-20

  The present invention relates to compositions for encapsulation of biomaterials in a silica-matrix. The present invention includes a composition for formation of a silica-matrix encapsulated biomaterial. The composition includes a reactive silicon compound and a biomaterial with a catalytic activity. When encapsulated in the silica-matrix, the biomaterial at least partially retains its catalytic activity. The present invention also relates to methods of making silica-matrix encapsulated biomaterials, and to methods of using silica-matrix encapsulated biomaterials, including methods of treating water or gas using the silica-matrix encapsulated biomaterials.
• US9790484B2
  申请人：——

  公开号：US9790484B2

  公开（公告）日：2017-10-17
• [EN] SILICA ENCAPSULATED BIOMATERIALS<br/>[FR] BIOMATÉRIAUX ENCAPSULÉS DANS DE LA SILICE
  申请人：WACKETT LAWRENCE P

  公开号：WO2012116013A2

  公开（公告）日：2012-08-30

  The present invention relates to compositions for encapsulation of biomaterials in a silica-matrix. The present invention includes a composition for formation of a silica-matrix encapsulated biomaterial. The composition includes a reactive silicon compound and a biomaterial with a catalytic activity. When encapsulated in the silica-matrix, the biomaterial at least partially retains its catalytic activity. The present invention also relates to methods of making silica-matrix encapsulated biomaterials, and to methods of using silica-matrix encapsulated biomaterials, including methods of treating water or gas using the silica-matrix encapsulated biomaterials.