2-bromo-6-(3-bromophenyl)naphthalene | 944801-48-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-bromo-6-(3-bromophenyl)naphthalene
• CAS: 944801-48-3
• 化学式: C₁₆H₁₀Br₂
• 分子量: 362.063
• InChiKey: HQTAHJWZVDGPAK-UHFFFAOYSA-N

物化性质

• 沸点：
  431.9±25.0 °C(Predicted)
• 密度：
  1.636±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (10-苯基蒽-9-基)硼酸 、 2-bromo-6-(3-bromophenyl)naphthalene 在 四(三苯基膦)钯 potassium carbonate 作用下， 以 水 、 苯甲醚 为溶剂， 反应 24.0h， 以75%的产率得到9-Phenyl-10-[3-[6-(10-phenylanthracen-9-yl)naphthalen-2-yl]phenyl]anthracene
  参考文献：
  名称：

  WO2007/86695

  摘要：

  公开号：
• 作为产物：
  描述：

  dimethyl 2-(3-bromophenyl)cyclopropane-1,1-dicarboxylate 在 gallium(III) trichloride 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以67%的产率得到2-bromo-6-(3-bromophenyl)naphthalene
  参考文献：
  名称：

  Unexpected formation of substituted naphthalenes and phenanthrenes in a GaCl3 mediated dimerization–fragmentation reaction of 2-arylcyclopropane-1,1-dicarboxylates

  摘要：

  Dimethyl 2-arylcyclopropane-1,1-dicarboxylates on heating with GaCl3 undergo dimerization to afford arylnaphthalenes or phenanthrenes. A possible reaction mechanism including elimination of two dimethyl malonate molecules was proposed, dimethyl malonate gallium complex Ga3+[H2C(CO2Me)(2)}](3)(GaCl4-)(3) was isolated and characterized by X-ray diffraction analysis.

  DOI：

  10.1016/j.mencom.2014.11.011

文献信息

• Synthesis of 2-phenylnaphthalenes from styrene oxides using a recyclable Brønsted acidic [HNMP]⁺HSO₄⁻ ionic liquid
  作者：Kishor V. Wagh、Bhalchandra M. Bhanage

  DOI：10.1039/c5gc01170a

  日期：——

  This work reports novel and efficient protocol for the synthesis of 2-phenylnaphthalenes from styrene oxides using recylable ionic liquid. The ionic liquid N-methyl-2-pyrrolidone hydrogensulfate [HNMP]+HSO4- played a dual role of...

  这项工作报告了新颖和有效的协议，使用可再离子化的离子液体从苯乙烯氧化物合成2-苯基萘。离子液体N-甲基-2-吡咯烷酮硫酸氢盐[HNMP] + HSO4-发挥了双重作用。
• Lewis Acid Promoted Homodimerization of Styrene Diols: An Efficient Approach toward 2-Phenylnaphthalenes
  作者：Chinmoy Kumar Hazra、Rina Mahato、Jabir Khan、Aparna Tyagi

  DOI：10.1055/s-0042-1751376

  日期：2023.4

  We report a straightforward, metal-free, efficient protocol for the synthesis of 2-phenylnaphthalenes from 1-phenylethane-1,2-diols under mild conditions. In this strategy, 1,1,1,3,3,3-hexafluoro-2-propanol is used as a solvent that stabilizes the reaction intermediate. An in situ IR experiment revealed that the reaction proceeds through the formation of phenylacetaldehyde followed by a [4+2] Diels–Alder

  我们报告了一种在温和条件下从 1-苯基乙烷-1,2-二醇合成 2-苯基萘的简单、无金属、有效的方案。在该策略中，1,1,1,3,3,3-六氟-2-丙醇用作稳定反应中间体的溶剂。原位 IR 实验表明，该反应通过苯乙醛的形成以及 [4+2] Diels-Alder 反应进行。进行了几个对照实验以获得对反应的机理见解。
• New Anthracene Derivatives, Preparation Method Thereof and Organic Light Emitting Diode Using the Same
  申请人：Kim Kong-Kyeom

  公开号：US20100252817A1

  公开（公告）日：2010-10-07

  The present invention provides a novel anthracene derivative, a method for preparing the same, and an organic electronic device using the same. The anthracene derivative according to the invention can function alone as a light emitting host, in particular, as a blue host in an organic electronic device. Further, the anthracene derivative according to the invention can also function as a hole injecting or hole transporting material, an electron injecting or electron transporting material, or a light emitting material in an organic electronic device including a light emitting device. Therefore, the organic electronic device according to the present invention shows excellent characteristics in efficiency, drive voltage and stability.
• US8957407B2
  申请人：——

  公开号：US8957407B2

  公开（公告）日：2015-02-17