4-(3-hydroxypropyl)-1,3-dioxolan-2-one | 1085937-45-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: 4-(3-hydroxypropyl)-1,3-dioxolan-2-one
• 英文别名: 4-(3-Hydroxypropyl)-1,3-dioxolane-2-one
• CAS: 1085937-45-6
• 化学式: C₆H₁₀O₄
• 分子量: 146.143
• InChiKey: DQRGHASKJMHEPJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.7
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-戊烯-1-醇 、 碳酸氢钠 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 水 、 丙酮 为溶剂， 反应 18.0h， 以65%的产率得到4-(3-hydroxypropyl)-1,3-dioxolan-2-one
  参考文献：
  名称：

  Microwave assisted synthesis of cyclic carbonates from olefins with sodium bicarbonates as the C1 source

  摘要：

  在微波加热下，使用NaHCO3作为C1来源，在丙酮–水体系中实现了烯烃向环碳酸酯的高效转化，其选择性和产率显著超过了传统加热所获得的结果。

  DOI：

  10.1039/c4cc00252k

文献信息

• Isocyanate-free synthesis of carbonate-modified polymers
  申请人：Evonik Degussa GmbH

  公开号：US10202488B2

  公开（公告）日：2019-02-12

  The present invention relates to an isocyanate-free and preferably solvent-free process for preparing polymers containing five-membered cyclic carbonate groups. In particular, the present invention is directed to a process for preparing polymers bearing cyclic carbonate groups by reacting carboxyl-bearing polymers selected from the group including polyesters based on di- or polyols and di- or polycarboxylic acids or derivatives thereof or poly(meth)acrylates, with hydroxyl-functionalized five-membered cyclic carbonates, without addition of isocyanates.

  本发明涉及一种用于制备含有五元环碳酸酯基团的聚合物的无异氰酸酯且优选无溶剂工艺。特别是，本发明涉及一种制备含环状碳酸酯基团的聚合物的工艺，该工艺是在不添加异氰酸酯的情况下，使选自基于二元或多元醇和二元或多元羧酸或其衍生物或聚（甲基）丙烯酸酯的聚酯组的含羧基聚合物与羟基官能化的五元环状碳酸酯反应。
• Electrocoating composition including an anti-crater agent
  申请人：AXALTA COATING SYSTEMS IP CO., LLC

  公开号：US10577510B2

  公开（公告）日：2020-03-03

  An electrocoating composition is provided herein. The electrocoating composition includes an aqueous carrier. The electrocoating composition further includes a film forming binder. The film forming binder includes an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent. The electrocoating composition further includes an anti-crater agent selected from the group of a polyester resin dispersion, a polyacrylate resin dispersion, and a combination thereof. The electrocoating composition further includes a supplemental anti-crater agent including a polyether modified polysiloxane.

  本文提供了一种电涂层组合物。电涂层组合物包括水性载体。电涂层组合物还包括成膜粘合剂。成膜粘合剂包括环氧胺加合物和封端多异氰酸酯交联剂。电涂层组合物还包括一种防缩孔剂，选自聚酯树脂分散体、聚丙烯酸酯树脂分散体及其组合。电涂层组合物还包括一种补充抗缩孔剂，包括聚醚改性聚硅氧烷。
• Cathodic electrocoating compositions containing hydroxyl-carbonate blocked polyisocyanate crosslinking agent
  申请人：——

  公开号：US20030064227A1

  公开（公告）日：2003-04-03

  An improved aqueous cathodic electrocoating composition having a binder of an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent; wherein the improvement is the use of a hydoxyl-carbonate blocked polyisocyanate crosslinking agent. Electrodeposited finishes are formed that have reduced weight loss when heated to cure.

  一种改进的水性阴极电涂层组合物，其粘结剂为环氧胺加合物和封端多异氰酸酯交联剂；其中改进之处在于使用了一种氢氧碳酸酯封端多异氰酸酯交联剂。形成的电泳饰面在加热固化时可减少重量损失。
• Cathodic electrocoating compositions containing an anti-crater agent
  申请人：Gam Allisa

  公开号：US20060084725A1

  公开（公告）日：2006-04-20

  An improved aqueous cathodic electrocoating composition that contains an anti-crater agent which is a water-reducible polyester resin having an acid value less than 40 mg KOH/g. The water-reducible polyester is the reaction product of (1) a hydroxy cyclic carbonate; (2) a polycarboxylic acid anhydride; (3) optional monofunctional epoxy resin; (4) a polyfunctional isocyanate resin; and, (5) a polyamine compound containing tertiary amine and either primary or secondary functionality. The reaction product is neutralized in the presence of acid and water to convert the tertiary amine groups to water-dilutable groups. Hydrolyzable silane groups can also be incorporated into the reaction product to further enhance its crater resistance property. The electrocoat composition produces coatings having a smoother appearance with fewer craters without adversely affecting intercoat adhesion of the cured film to subsequent coating layers applied thereover.

  一种改进的水性阴极电涂层组合物，其中含有一种防缩孔剂，它是一种酸值小于 40 毫克 KOH/g 的水溶性聚酯树脂。该水还原性聚酯是以下物质的反应产物：(1) 环碳酸羟酯；(2) 聚羧酸酐；(3) 任选的单官能环氧树脂；(4) 多官能异氰酸酯树脂；以及 (5) 含有叔胺和伯胺或仲胺官能团的多胺化合物。反应产物在酸和水的存在下进行中和，将叔胺基团转化为可稀释的水基。可水解硅烷基团也可加入反应产物中，以进一步增强其抗缩孔性能。这种电涂层组合物生产出的涂层外观更平滑，凹坑更少，同时不会对固化薄膜与后续涂层的层间附着力产生不利影响。
• CATHODIC ELECTROCOATING COMPOSITIONS CONTAINING HYDROXYL-CARBONATE BLOCKED POLYISOCYANATE CROSSLINKING AGENT
  申请人：E.I. du Pont de Nemours and Company

  公开号：EP1425354B1

  公开（公告）日：2005-03-16