D-Glucitol, 1,3:2,4-bis-O-((4-ethylphenyl)methylene)- | 80124-42-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二恶烷
• 英文名称: D-Glucitol, 1,3:2,4-bis-O-((4-ethylphenyl)methylene)-
• 英文别名: (1R)-1-[(4R,4aR,8aS)-2,6-bis(4-ethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol
• CAS: 80124-42-1
• 化学式: C₂₄H₃₀O₆
• 分子量: 414.5
• InChiKey: RPMMDFYGVMKCJU-JJKKTNRVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  30
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  77.4
• 氢给体数：
  2
• 氢受体数：
  6

文献信息

• HEXAGONAL DIACETAL CRYSTAL, NUCLEATING AGENT CONTAINING THE HEXAGONAL CRYSTAL, POLYOLEFIN RESIN COMPOSITION CONTAINING THE HEXAGONAL CRYSTAL, MOLDED ARTICLES OF THE COMPOSITION, AND PROCESS FOR MOLDING THE COMPOSITION
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0816365A1

  公开（公告）日：1998-01-07

  This invention provides hexagonal crystals of a diacetal represented by the formula (1) wherein R1 and R2 each represents an alkyl group having 1 to 4 carbon atoms or a halogen atom, each of m and n is an integer of 0 to 2 and p is 0 or 1, a nucleating agent comprising the diacetal of the formula (1), wherein part or the whole of the diacetal is in the form of hexagonal crystals, a polyolefin resin composition and a molded product each comprising a polyolefin resin and the nucleating agent, and a method for molding the polyolefin resin composition. According to the invention, the occurrence of fish eyes and coloration in a molded product can be prevented, the optical, mechanical and thermal properties of the molded product are superior and the molding cycle is shortened.

  本发明提供了由式（1）表示的二缩醛的六方晶体 其中 R1 和 R2 分别代表具有 1 至 4 个碳原子的烷基或卤素原子，m 和 n 分别为 0 至 2 的整数，p 为 0 或 1；包含式（1）二缩醛的成核剂，其中部分或全部二缩醛呈六方晶体状；包含聚烯烃树脂和成核剂的聚烯烃树脂组合物和模塑产品；以及模塑聚烯烃树脂组合物的方法。 根据本发明，可以防止模塑产品出现鱼眼和色斑，提高模塑产品的光学、机械和热性能，缩短模塑周期。
• METHOD FOR RECRYSTALLIZING DIACETAL IN POLYOLEFIN RESIN
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0953598A1

  公开（公告）日：1999-11-03

  The present invention relates to a method for recrystallizing diacetal, such as 1,3:2,4-bis-O-(benzylidene)-D-sorbitol or a nuclearly substituted derivative thereof, in a polyolefin resin without giving a yellowish tint to the polyolefin resin; a polyolefin resin molded article containing a recrystallized diacetal which is obtainable by said recrystallization method; a method for producing polyolefin resin pellets containing the recrystallized diacetal by utilizing said recrystallization method, and polyolefin resin pellets obtainable by the above method; and a method for producing a polyolefin resin molded article by heating and melting said pellets at a temperature not lower than its sol-gel transition temperature during the heating cycle and rapidly cooling the melt; and a polyolefin resin molded article obtainable by said method.

  本发明涉及一种在聚烯烃树脂中重结晶二缩醛（如 1，3：2,4-双-O-(亚苄基)-D-山梨醇或其核取代衍生物在聚烯烃树脂中重结晶而不使聚烯烃树脂呈黄色的方法；含有通过所述重结晶方法获得的重结晶二缩醛的聚烯烃树脂成型品；利用上述重结晶方法生产含有重结晶二缩醛的聚烯烃树脂颗粒的方法，以及通过上述方法获得的聚烯烃树脂颗粒；以及通过在加热循环期间以不低于溶胶-凝胶转变温度的温度加热和熔化上述颗粒并迅速冷却熔体，生产聚烯烃树脂模塑品的方法；以及通过上述方法获得的聚烯烃树脂模塑品。
• DIACETAL COMPOSITION, PROCESS FOR THE PREPARATION OF THE SAME, NUCLEATING AGENT FOR POLYOLEFINS CONTAINING THE SAME, POLYOLEFIN RESIN COMPOSITIONS, AND MOLDINGS
  申请人：NEW JAPAN CHEMICAL CO.,LTD.

  公开号：EP0962459A1

  公开（公告）日：1999-12-08

  This invention provides a granular or powdery diacetal composition comprising: (a) at least one diacetal such as 1,3:2,4-O-dibenzylidene-D-sorbitol or a nucleus-substituted derivative thereof, and (b) at least one binder selected from the group consisting of neutral or weakly acidic monovalent organic acids, neutral or weakly acidic polyvalent organic acids, partial salts of neutral or weakly acidic polyvalent organic acids, salts of sulfuric acid ester, sulfonic acid salts, salts of phosphoric acid ester, phosphoric acid esters, phosphorous acid esters and aluminum salts of a neutral or weakly acidic monovalent organic acid, the binder being uniformly dispersed on the surface and in the interior of the particles of the granular or powdery diacetal composition; a process for preparing the composition; a polyolefin resin nucleating agent comprising the composition; a resin composition containing the nucleating agent and a polyolefin resin; and a polyolefin resin molded article.

  本发明提供了一种颗粒状或粉末状的二缩醛组合物，其中包括 (a) 至少一种二缩醛，如 1,3:2,4-O-二亚苄基-D-山梨醇或其核取代衍生物，和 (b) 至少一种粘合剂，该粘合剂选自以下组别：中性或弱酸性一价有机酸、中性或弱酸性多价有机酸、中性或弱酸性多价有机酸的部分盐、硫酸酯盐、磺酸盐、磷酸酯盐、磷酸酯盐、磷酸酯、磷酸酯和中性或弱酸性单价有机酸的铝盐，粘合剂均匀地分散在颗粒状或粉末状二缩醛组合物的颗粒表面和内部；制备该组合物的工艺；包含该组合物的聚烯烃树脂成核剂；包含成核剂和聚烯烃树脂的树脂组合物；以及聚烯烃树脂模塑制品。
• PROPYLENE POLYMER COMPOSITION AND FILMS MADE THEREFROM
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1006149A1

  公开（公告）日：2000-06-07

  A propylene homopolymer or a copolymer of propylene and an α-olefin with at least 4 carbon atoms, which is produced through polymerization in the presence of a metallocene catalyst and which has an increased isotactic pentad fraction and a reduced molecular weight distribution; and also a propylene-based polymer composition as prepared by adding a nucleating agent to the homopolymer or the copolymer are superior to conventional polymers and polymer compositions, as they have well-balanced toughness and heat-sealability, and are not sticky, and, in addition, they have excellent anti-blocking properties. Their films especially those for wrapping and packaging edibles are tough and have excellent anti-blocking properties, and high film impact resistance. The polymer and the polymer composition have good moldability.

  一种丙烯均聚物或丙烯与至少含有 4 个碳原子的 α-烯烃的共聚物，是在茂金属催化剂存在下通过聚合反应制得的，它具有更高的异构五元组分和更低的分子量分布；以及在均聚物或共聚物中加入成核剂制备的丙烯基聚合物组合物，其韧性和热封性能均衡，不粘手，具有优异的抗阻塞性能，因此优于传统的聚合物和聚合物组合物。它们生产的薄膜，尤其是用于包装食品的薄膜，韧性好，具有优异的抗阻塞性能和较高的薄膜抗冲击性。聚合物和聚合物组合物具有良好的成型性。
• PROPYLENE POLYMERS AND RESIN COMPOSITION AND MOLDING CONTAINING THE POLYMERS
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1227112A1

  公开（公告）日：2002-07-31

  The propylene polymer of the present invention satisfies (1) a 25°C hexane soluble content (H25) of 0-80 wt%; and (2) either no melting temperature (Tm) measurable by differential scanning calorimetry (DSC), or a melting temperature (Tm) satisfying, if measurable by DSC, the following relationship: ΔH≧3 x (Tm - 120) wherein ΔH is a melting endotherm (J/g). The propylene homopolymer of the present invention satisfies (1) a meso pentad fraction (mmmm) of 30-60 mol%; (2) a racemic pentad fraction (rrrr) satisfying the following relationship: [rrrr/(1-mmmm)]≦0.1; (3) a fraction (W25) eluted at a temperatures up to 25°C by temperature-programmed chromatography, of from 20-100 wt%; and, (4) a pentad fraction (rmrm) of more than 2.5 mol%. The propylene copolymer of the present invention satisfies (1) a stereoregularity index (P) of 55-90 mol% as determined by 13C-NMR measurement; and (2) a fraction (W25) eluted at a temperatures up to 25°C by temperature-programmed chromatography, of from 20-100 wt%.

  本发明的丙烯聚合物满足(1)25℃己烷可溶物含量(H25)为0-80 wt%；和(2)没有可通过差示扫描量热法(DSC)测量的熔化温度(Tm)，或者熔化温度(Tm)满足(如果可通过 DSC 测量)以下关系：ΔH≧3 x (Tm - 120)，其中ΔH 是熔化内热(J/g)。本发明的丙烯均聚物满足以下条件：(1) 中间五元组分 (mmmm) 为 30-60 mol%；(2) 外消旋五元组分 (rrrr) 满足以下关系：[rrrr/(1-mmmm)]≦0.1；(3)通过温度程序色谱法在最高 25℃的温度下洗脱的馏分(W25)为 20-100 wt%；(4)五元组分(rmrm)超过 2.5 mol%。本发明的丙烯共聚物满足以下条件：(1)通过 13C-NMR 测量确定的立体规整度指数 (P) 为 55-90 摩尔%；(2)通过温度程序色谱法在最高 25°C 的温度下洗脱的馏分 (W25) 为 20-100 wt%。