1,2-Diphenylethane-1,2-diol;nitric acid | 58286-69-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,2-Diphenylethane-1,2-diol;nitric acid
• 英文别名: 1,2-diphenylethane-1,2-diol;nitric acid
• CAS: 58286-69-4
• 化学式: C14H16N2O8
• 分子量: 340.28
• InChiKey: IKARBJBVOAYVEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.76
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  173
• 氢给体数：
  4
• 氢受体数：
  8

文献信息

• A process for the production of high energy material
  申请人：Secretary of State for Defence in Her Britannic Majesty's Gov. of the United Kingdom of Great Britain and Northern Ireland

  公开号：EP0223440A1

  公开（公告）日：1987-05-27

  A process for the production of a high energy nitrate ester involves reacting, in an inert organic solvent, a heterocyclic compound, selected from oxiranes, oxetanes, N-substituted aziridines and N-substituted azetidines, with either N204 or N205, and when the compound is reacted with N204, oxidising the 0- or N-nitrate substituents or substituent in the product to O-or N- nitrate substituent or substituents. The remaining ring carbon atoms on the heterocyclic compound may be substituted or unsubstituted. Preferred substituent groups for the C and/or N ring atoms on the compound include alkyl, cyanoalkyl, haloalkyl, nitroalkyl, and substituted aryl. Several novel nitrate ester are also provided, including nitrated derivatives of polybutadiene, in which between 1 % and 25% of the carbon atoms in the polymer are substituted by vicinal nitrate ester (-ON02) groups.

  生产高能硝酸酯的工艺包括在惰性有机溶剂中，将选自环氧乙烷、环氧杂环丁烷、N-取代的氮杂环丁烷和 N-取代的氮杂环丁烷的杂环化合物与 N204 或 N205 反应，当该化合物与 N204 反应时，将产物中的 0-或 N-硝酸酯取代基或取代基氧化为 O-或 N-硝酸酯取代基或取代基。杂环化合物上剩余的环碳原子可以是取代或未取代的。化合物上 C 和/或 N 环原子的首选取代基包括烷基、氰基烷基、卤代烷基、硝基烷基和取代芳基。 此外，还提供了几种新型硝酸酯，包括聚丁二烯的硝化衍生物，其中聚合物中 1% 至 25% 的碳原子被邻位硝酸酯（-ON02）基团取代。
• US4985584A
  申请人：——

  公开号：US4985584A

  公开（公告）日：1991-01-15