Carbonic acid methyl ester 4-methylene-cyclohexylmethyl ester | 61223-54-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: Carbonic acid methyl ester 4-methylene-cyclohexylmethyl ester
• 英文别名: Methyl (4-methylidenecyclohexyl)methyl carbonate；methyl (4-methylidenecyclohexyl)methyl carbonate
• CAS: 61223-54-9
• 化学式: C₁₀H₁₆O₃
• 分子量: 184.235
• InChiKey: BWCRALGQCFTKLI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  methyl cyanodithioformate 、 Carbonic acid methyl ester 4-methylene-cyclohexylmethyl ester 以 甲苯 为溶剂， 生成 Carbonic acid 4-(cyano-methylsulfanyl-methylsulfanylmethyl)-cyclohex-3-enylmethyl ester methyl ester
  参考文献：
  名称：

  Allylic cyanobis(methylthio)methylation. Insertion of a functionalized carbon in an allylic carbon-hydrogen bond

  摘要：

  DOI：

  10.1021/ja00438a082

文献信息

• PRODUCTION METHOD OF POLYCARBONATE, AND POLYCARBONATE PELLET
  申请人：Mitsubishi Chemical Corporation

  公开号：US20140031513A1

  公开（公告）日：2014-01-30

  The present invention relates to a method for producing a polycarbonate having excellent characteristics such as hue and mechanical properties with a stable quality and a high yield by solving a plurality of problems as those described above in producing a polycarbonate by using a specific dihydroxy compound exhibiting low thermal stability as compared with bisphenols and having a —CH 2 —O— structure. The polycarbonate obtained by polycondensation in the present invention is a polycarbonate having an appropriate viscosity despite decrease in the reaction temperature, providing for a color tone less susceptible to yellowing, and exhibiting excellent mechanical properties.
• US8785565B2
  申请人：——

  公开号：US8785565B2

  公开（公告）日：2014-07-22