CrMn3, σ | 12338-61-3

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: CrMn3, σ
• 英文别名: Chromium--manganese (1/3)；chromium;manganese
• CAS: 12338-61-3
• 化学式: CrMn₃
• 分子量: 216.81
• InChiKey: XCNJCXWPYFLAGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  铬 、 锰 以 melt 为溶剂， 生成 CrMn3, σ
  参考文献：
  名称：

  Some magnetic properties of σ-phase CrMn3

  摘要：

  The low-field magnetic susceptibility and the thermal expansion were measured from room temperature to 4.2 K, as well as the magnetization up to 50 kOe from about 100 to 4.2 K on a polycrystalline sample of sigma-phase CrMn3. The susceptibility results showed the existence of a weak ferromagnetic transition at T(c) = (86.2 +/- 0.3)K. The spontaneous magnetization at 4.2 K has a value of 0.256 emu/g and a high-field susceptibility of 17.2 x 10(-6) emu/g Oe. The average moment per atom is about 0.01-mu(B), while if all of the moments resided on the Mn atoms, it would be 0.013-mu(B). Since most of the average moments per atom cited for CrMn alloys are about 0.85-mu(B), it appears that the weak ferromagnetism in these alloys must be due to the canting of the moments.

  DOI：

  10.1016/0304-8853(92)91657-f

文献信息

• Some magnetic properties of σ-phase CrMn3
  作者：A.S. Pavlovic

  DOI：10.1016/0304-8853(92)91657-f

  日期：1992.2

  The low-field magnetic susceptibility and the thermal expansion were measured from room temperature to 4.2 K, as well as the magnetization up to 50 kOe from about 100 to 4.2 K on a polycrystalline sample of sigma-phase CrMn3. The susceptibility results showed the existence of a weak ferromagnetic transition at T(c) = (86.2 +/- 0.3)K. The spontaneous magnetization at 4.2 K has a value of 0.256 emu/g and a high-field susceptibility of 17.2 x 10(-6) emu/g Oe. The average moment per atom is about 0.01-mu(B), while if all of the moments resided on the Mn atoms, it would be 0.013-mu(B). Since most of the average moments per atom cited for CrMn alloys are about 0.85-mu(B), it appears that the weak ferromagnetism in these alloys must be due to the canting of the moments.