Eu(tta)3(2,6-bis[4-(3,4-ethylenedioxythien-2-yl)pyrazol-1-yl]pyridine) | 1211894-70-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并二恶烷
• 英文名称: Eu(tta)3(2,6-bis[4-(3,4-ethylenedioxythien-2-yl)pyrazol-1-yl]pyridine)
• 英文别名: Eu(2-thenoyltrifluoroacetonate)3(2,6-bis[4-(3,4-ethylenedioxythien-2-yl)pyrazol-1-yl]pyridine)
• CAS: 1211894-70-0
• 化学式: C₄₇H₂₉EuF₉N₅O₁₀S₅
• 分子量: 1307.05
• InChiKey: ROMVIHBMIHVFKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  europium tris[1-(α-thienyl)-4,4,4-trifluorobutane-1,3-dionate] dihydrate 、 2,6-bis[4-[2-(3,4-diethylenedioxy)thiophene]pyrazol-1-yl]-pyridine 以 甲苯 为溶剂， 生成 Eu(tta)3(2,6-bis[4-(3,4-ethylenedioxythien-2-yl)pyrazol-1-yl]pyridine)
  参考文献：
  名称：

  Europium Complexes of a Novel Ethylenedioxythiophene-Derivatized Bis(pyrazolyl)pyridine Ligand Exhibiting Efficient Lanthanide Sensitization

  摘要：

  A new class of highly luminescent nine-coordinated europium(III) tris(beta-diketonate) bis[(ethylenedioxythiophene)pyrazolyl]pyridine (L) complexes has been synthesized and the photophysical properties studied: 1=Eu(hfac)(3)(L); 2=Eu(tta)(3)(L); 3=Eu(btfac)(3)-(L). The solid-state structure of complex 1 has been determined by single-crystal X-ray crystallography and shows the geometry of the local coordination environment around the Eu-III ion to be a slightly distorted tricapped trigonal prism. Luminescence lifetimes were found to be 581, 473, and 576 mu s for complexes 1-3, respectively, Absolute quantum yields for complexes 1-3 were measured as 16.4 +/- 1.4%, 27.5 +/- 1.2%, and 22.2% +/- 0.3%, respectively.

  DOI：

  10.1021/ic902481y