{Cu(H2O)2((+)-Phos)((-)-Phos)} | 140655-91-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: {Cu(H2O)2((+)-Phos)((-)-Phos)}
• CAS: 140655-91-0
• 化学式: C₄₀H₂₈CuO₁₀P₂
• 分子量: 794.15
• InChiKey: DCVLPSPQSFUBTA-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  {Cu(CH3OH)2(H2O)3}((+)-Phos)((-)-Phos) 以 neat (no solvent) 为溶剂， 生成 {Cu(H2O)2((+)-Phos)((-)-Phos)}
  参考文献：
  名称：

  Reaction of (±)-1,1′-binaphthyl-2,2′-diyl hydrogen phosphate {(±)-phosH} with copper(II), cobalt(II) and iron(II) compounds; Identification by x-ray diffraction of [Co(CH3OH)4(H2O)2][(+)-phos][(−)-phos]. 2CH3OH·H2O

  摘要：

  [Cu2(mu-O2CCH3)4(H2O)2], [CuCO3.Cu(OH)2], [CoSO4.7H2O], [Co((+)-tartrate)], and [FeSO4.7H2O] react with excess racemic (+/-)-1,1'-binaphthyl-2,2'-diyl hydrogen phosphate {(+/-)-PhosH} to give mononuclear Cu(II), Co(II) and Fe(II) products. The cobalt product, [Co(CH3OH)4(H2O)2]((+)-Phos)((-)-Phos).2CH3OH.H2O (7), has been identified by X-ray diffraction. The high-spin, octahedral Co(II) atom is ligated by four equatorial methanol molecules and two axial water molecules. A (+)- and a (-)-Phos- ion are associated with each molecule of the complex but are not coordinated to the metal centre. For the other Co(II), Cu(II) and Fe(II) samples of similar formulation to (7) it is also thought that the Phos- ions are not bonded directly to the metal. When some of the Cu(II) and Co(II) samples are heated under high vacuum there is evidence that the Phos- ions are coordinated directly to the metals in the products.

  DOI：

  10.1016/s0277-5387(00)86178-1