3-氯丙基三氯硅烷 | 253586-30-0

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 3-氯丙基三氯硅烷
• 英文名称: 3-chloropropyltrichlorosilane
• 英文别名: 3-chloropropylchlorodimethoxysilane；Chloro-(3-chloropropyl)-dimethoxysilane
• CAS: 253586-30-0
• 化学式: C₅H₁₂Cl₂O₂Si
• 分子量: 203.141
• InChiKey: WPCSWVPIPCNXIO-UHFFFAOYSA-N

物化性质

• 沸点：
  178.2±23.0 °C(Predicted)
• 密度：
  1.114±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.09
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-氯丙基三氯硅烷 在 tetra(tert-butoxy)silane 、 吡啶 作用下， 以 正己烷 、 甲醇 为溶剂， 反应 3.0h， 生成 C₂₀H₄₈Cl₄O₁₂Si₅
  参考文献：
  名称：

  Direct alkoxysilylation of alkoxysilanes for the synthesis of explicit alkoxysiloxane oligomers

  摘要：

  Direct alkoxysilylation, which is a powerful tool to provide explicit alkoxysiloxanes, is developed and its versatility is investigated. Siloxane pentamers Si[OSiR1(OMe)(2)](4) having various functional groups (R-1 = methyl, vinyl, phenyl, chloropropyl and n-butyl groups) were successfully obtained by direct alkoxysilylation of Si(OR)(4) (R= t-Bu, CHPh2). Thus, the versatility of the reaction is confirmed on organic functional groups R-1. Functional group tolerance of the reaction is discussed on the basis of electro-negativity of the R-1 groups. Alkoxysilylation of Si(Ot-Bu)(2)(OMe)(2) and Si(Ot-Bu)(OMe)(3) selectively gives trimer (MeO)(2)Si[OSiMe(OMe)(2)](2) and dimer (MeO)(3)SiOSiMe(OMe)(2), respectively. Thus, the feasibility on siloxane structure is also confirmed. Various siloxane compounds are synthesized by this newly developed reaction for the first time. (C) 2012 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2012.05.033
• 作为产物：
  描述：

  甲基叔丁基醚 、 3-氯丙基三氯硅烷 在 bismuth(III) chloride 作用下， 以 乙腈 为溶剂， 生成 3-氯丙基三氯硅烷
  参考文献：
  名称：

  Direct alkoxysilylation of alkoxysilanes for the synthesis of explicit alkoxysiloxane oligomers

  摘要：

  Direct alkoxysilylation, which is a powerful tool to provide explicit alkoxysiloxanes, is developed and its versatility is investigated. Siloxane pentamers Si[OSiR1(OMe)(2)](4) having various functional groups (R-1 = methyl, vinyl, phenyl, chloropropyl and n-butyl groups) were successfully obtained by direct alkoxysilylation of Si(OR)(4) (R= t-Bu, CHPh2). Thus, the versatility of the reaction is confirmed on organic functional groups R-1. Functional group tolerance of the reaction is discussed on the basis of electro-negativity of the R-1 groups. Alkoxysilylation of Si(Ot-Bu)(2)(OMe)(2) and Si(Ot-Bu)(OMe)(3) selectively gives trimer (MeO)(2)Si[OSiMe(OMe)(2)](2) and dimer (MeO)(3)SiOSiMe(OMe)(2), respectively. Thus, the feasibility on siloxane structure is also confirmed. Various siloxane compounds are synthesized by this newly developed reaction for the first time. (C) 2012 Published by Elsevier B.V.

  DOI：

  10.1016/j.jorganchem.2012.05.033

文献信息

• [EN] PROCESS FOR MAKING HALOORGANOALKOXYSILANES<br/>[FR] PROCÉDÉ DE FABRICATION DES HALOORGANOALCOXYSILANES
  申请人：GEN ELECTRIC

  公开号：WO2005118598A1

  公开（公告）日：2005-12-15

  A haloorganoalkoxysilane is prepared by reacting an olefinic halide with an alkoxysilane in which the alkoxy group(s) contain at least two carbon atoms in a reaction medium to which has been added a catalytically effective amount of ruthenium-containing catalyst and a reaction-promoting effective amount of an electron-donating aromatic compound promoter. The process can be used to prepare, inter alia, chloropropyltriethoxysilane, which is a key intermediate in the manufacture of silane coupling agents.

  通过在反应介质中加入含有催化作用的含钌催化剂和电子捐赠芳香化合物促进剂的有效量，将含有至少两个碳原子的烷氧基的烯丙基卤化物与烷氧基硅烷反应制备出卤代丙基三乙氧基硅烷，该过程可用于制备硅烷偶联剂的关键中间体。
• Process for making haloorganoalkoxysilanes
  申请人：CROMPTON CORPORATION

  公开号：US20040176627A1

  公开（公告）日：2004-09-09

  A haloorganoalkoxysilane is prepared by reacting an olefinic halide with an alkoxysilane in which the alkoxy group(s) contain at least two carbon atoms in a reaction medium to which has been added a catalytically effective amount of ruthenium-containing catalyst and a reaction-promoting effective amount of an electron-donating aromatic compound promoter. The process can be used to prepare, inter alia, chloropropyltriethoxysilane, which is a key intermediate in the manufacture of silane coupling agents.

  一种卤代烯与含有至少两个碳原子的烷氧基硅烷在反应介质中反应制备出一种卤代有机烷氧基硅烷，反应介质中加入含有铑催化剂的催化剂和电子给体芳香化合物促进剂的反应促进剂。该方法可用于制备氯丙基三乙氧基硅烷，该化合物是硅烷偶联剂制造中的关键中间体。
• Synthesis of a multifunctional alkoxysiloxane oligomer
  作者：Masashi Yoshikawa、Ryutaro Wakabayashi、Misa Tamai、Kazuyuki Kuroda

  DOI：10.1039/c4nj00204k

  日期：——

  The siloxane bonds of oligomer 1 were not cleaved by hydrolysis, indicating the suitability of 1 for controlled hybrid preparation.

  寡聚物1的硅氧烷键没有被水解断裂，表明寡聚物1适用于控制杂化制备。
• CN117105969
  申请人：——

  公开号：——

  公开（公告）日：——
• Direct alkoxysilylation of alkoxysilanes for the synthesis of explicit alkoxysiloxane oligomers
  作者：Ryutaro Wakabayashi、Misa Tamai、Kazufumi Kawahara、Hiroki Tachibana、Yutaka Imamura、Hiromi Nakai、Kazuyuki Kuroda

  DOI：10.1016/j.jorganchem.2012.05.033

  日期：2012.10

  Direct alkoxysilylation, which is a powerful tool to provide explicit alkoxysiloxanes, is developed and its versatility is investigated. Siloxane pentamers Si[OSiR1(OMe)(2)](4) having various functional groups (R-1 = methyl, vinyl, phenyl, chloropropyl and n-butyl groups) were successfully obtained by direct alkoxysilylation of Si(OR)(4) (R= t-Bu, CHPh2). Thus, the versatility of the reaction is confirmed on organic functional groups R-1. Functional group tolerance of the reaction is discussed on the basis of electro-negativity of the R-1 groups. Alkoxysilylation of Si(Ot-Bu)(2)(OMe)(2) and Si(Ot-Bu)(OMe)(3) selectively gives trimer (MeO)(2)Si[OSiMe(OMe)(2)](2) and dimer (MeO)(3)SiOSiMe(OMe)(2), respectively. Thus, the feasibility on siloxane structure is also confirmed. Various siloxane compounds are synthesized by this newly developed reaction for the first time. (C) 2012 Published by Elsevier B.V.