ethyl 6-methoxycarbonyl-2-naphthoate | 1404433-24-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: ethyl 6-methoxycarbonyl-2-naphthoate
• 英文别名: 2-O-ethyl 6-O-methyl naphthalene-2,6-dicarboxylate
• CAS: 1404433-24-4
• 化学式: C₁₅H₁₄O₄
• 分子量: 258.274
• InChiKey: GVQNVAIMPUEELJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  (E)-ethyl α-ethynyl-4-methoxycarbonylcinnamate 在 氯化铂 作用下， 以 甲苯 为溶剂， 反应 0.33h， 以75%的产率得到ethyl 6-methoxycarbonyl-2-naphthoate
  参考文献：
  名称：

  铂催化芳基炔烃的氢芳基化反应合成萘†

  摘要：

  通过选择性的Pt催化乙基（E）-的6-内分子氢芳基化反应，开发了一种高效合成官能化萘的方法，该官能化萘在4位上具有氢，烷基，烯基，芳基或杂芳基，在2位上具有乙氧羰基。2-乙炔基/炔基肉桂酸酯。

  DOI：

  10.1021/ol302437v

文献信息

• COPOLYESTERIMIDES OF POLY(ALKYLENE NAPHTHALATE)S HAVING HIGH GLASS TRANSITION TEMPERATURE AND FILM MADE THEREFROM
  申请人：DUPONT TEIJIN FILMS U.S. LIMITED PARTNERSHIP

  公开号：US20140350210A1

  公开（公告）日：2014-11-27

  A copolyester comprising repeating units derived from an aliphatic glycol, naphthalene-dicarboxylic acid, and the monomer of formula (I) wherein n=2, 3 or 4, and films, fibres, moulding compositions and moulded articles made therefrom.
• COPOLYESTERIMIDES DERIVED FROM N,N'-BIS-(HYDROXYALKYL)-BENZOPHENONE-3,3',4,4'-TETRACARBOXYLIC DIIMIDE AND FILMS MADE THEREFROM
  申请人：SANKEY Stephen William

  公开号：US20160137790A1

  公开（公告）日：2016-05-19

  A semi-crystalline biaxially oriented film comprising a copolyester which comprises repeating units derived from an aliphatic glycol, an aromatic dicarboxylic acid, and the monomer of formula (I): (I) wherein n=2, 3 or 4, Z is C═0, and wherein comonomer (I) constitutes a proportion of the glycol fraction of the copolyester and is present in an amount of at least about 4 mol % of the glycol fraction of the copolyester.
• COPOLYESTERIMIDES DERIVED FROM N,N'-BIS-(HYDROXYALKYL)-PYROMELLITIC DIIMIDE AND FILMS MADE THEREFROM
  申请人：SANKEY STEPHEN WILLIAM

  公开号：US20160122475A1

  公开（公告）日：2016-05-05

  A polyester film comprising a copolyester which comprises repeating units derived from an aliphatic glycol, an aromatic dicarboxylic acid, and the monomer of formula (I): wherein n=2, 3 or 4, and wherein comonomer (I) constitutes a proportion of the glycol fraction of the copolyester.
• COPOLYESTERIMIDES DERIVED FROM N,N'-BIS-(HYDROXYALKYL)-3,3',4,4'-DIPHENYLSULFONETETRACARBOXYLIC DIIMIDE AND FILMS MADE THEREFROM
  申请人：SANKEY Stephen William

  公开号：US20160130399A1

  公开（公告）日：2016-05-12

  A copolyester comprising repeating units derived from an aliphatic glycol, an aromatic dicarboxylic acid, and the monomer of formula (I): (Formula (I)) wherein n=2, 3 or 4, Z is S(═O) 2 , and wherein comonomer (I) constitutes a proportion of the glycol fraction of the copolyester; and films, fibres, moulding compositions or moulded articles comprising said copolyester.
• COPOLYESTERIMIDES DERIVED FROM AROMATIC DICARBOXYLIC ACIDS AND ALIPHATIC GLYCOLS AND FILMS MADE THEREFROM
  申请人：SANKEY Stephen William

  公开号：US20160251476A1

  公开（公告）日：2016-09-01

  A film comprising a copolyester wherein said copolyester comprises repeating units derived from an aliphatic glycol, an aromatic dicarboxylic acid, and a comonomer (M) selected from the group consisting of N,N′-bis-(2-hydroxyalkyl)-bicyclo-[2,2,2]-oct-7-ene-2,3,5,6-tetracarboxylic diimide (BODI) and 2-hydroxyalkyl-2-[p-(2-hydroxyethoxycarbonyl)phenyl]-1,3-dioxo-2H-isoindole-5-carboxylate (DOIC), wherein the number of carbon atoms is the 2-hydroxyalkyl group is 2, 3 or 4, and wherein comonomer (M) constitutes a proportion of the glycol fraction of the copolyester.