The invention pertains to foamable thermoplastic fluoropolymer composition comprising:
at least one fluoropolymer [polymer (A)]; and
at least one perfluoroalkoxysulphonic derivative of either of formulae:
(Xn+)1/n−O3S—CF2CF2O—Rdf—OCF2CF2—SO3−(Xn+)1/n and
Rmf—OCF2CF2—SO3−(Xn+)1/n
wherein Rdf is a divalent C1-C12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom; Rmf is a monovalent C1-C12 perfluorocarbon group, possibly comprising one or more ethereal oxygen atom, optionally comprising heteroatoms, generally selected from S, N, P; X=H, a metal cation, or an ammonium group; n is the valence of the cation X, preferably 1 or 2.
本发明涉及可发泡热塑性含
氟聚合物组合物,该组合物包括
至少一种含
氟聚合物[聚合物(A)];以及
至少一种式中任一式的
全氟烷氧基
磺酸衍
生物:
(Xn+)1/n-
O3S-
CF2CF2O-Rdf-O
CF2CF2-SO3-(Xn+)1/n 和
Rmf-O
CF2CF2-SO3-(Xn+)1/n
其中 Rdf 是二价 C1-C12
全氟碳基团,可能包含一个或多个
乙醚氧原子;Rmf 是一价 C1-C12
全氟碳基团,可能包含一个或多个
乙醚氧原子,可选择包含杂原子,一般选自 S、N、P;X=H、
金属阳离子或
铵基团;n 是阳离子 X 的价数,最好是 1 或 2。