| 1607816-91-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• CAS: 1607816-91-0
• 化学式: C₆₈H₇₂N₂O₄P₂Pd₂
• 分子量: 1256.12
• InChiKey: PADYDHWJFSNZGM-ZAWLDYKFSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  、 1,4-双(二苯基膦)丁烷 以 二氯甲烷 为溶剂， 反应 14.0h， 以75%的产率得到
  参考文献：
  名称：

  Self-assembly of Schiff-base palladacycle-based discrete pseudo-macrocycles: Evidence for hemilability of oxalate ligand

  摘要：

  Bis-bidentate tetra-coordinated oxalato bridged binuclear Schiff-base palladacycles [Pd{C,N-k(2)-(4-R) C6H3CH=NC6H3-2,6-i-Pr-2](2)(mu-eta(2)-eta(2)-C2O4) (R = H; OMe) were synthesized. Reactions of mu-oxalato bridged Schiff-base palladacycles [Pd{C,N-k(2)-(4-R)C6H3CH=NC6H3-2,6-i-Pr-2](2)(mu-eta(2)-eta(2)-C2O4) (R = H; OMe) with 1,4-bis(diphenylphosphino)butane (dppb) and 1,4-bis(diphenylphosphino)pentane (dppp) generated discrete pseudo-macrocycles with 1,1 '-bicoordinated oxalato bridge. Unexpectedly, mu-oxalato bridged Schiff-base palladacycle [Pd(C,N-k(2)-C6H4CH-NC6H3-2,6-i-Pr-2)](2)(mu-eta(2)-eta(2)-C2O4) reacted with PPh3 to form unusual bidentate/monodentate tri-coordinated oxalato bridged binuclear cyclopalladated complex [Pd(C,N-k(2)-C6H4CH=NC6H3-2,6-i-Pr-2)(PPh3)](mu-eta(2)-eta(1)-C2O4)[Pd(C-k(1)-C6H4CH=NC6H3-2,6-i-Pr-2)(PPh3)]. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2014.02.020