trans, trans-[Ru(η2-N(O)C10H6-2-O)2(CO)(PBu3)2] (all-trans) | 263845-71-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: trans, trans-[Ru(η2-N(O)C10H6-2-O)2(CO)(PBu3)2] (all-trans)
• CAS: 263845-71-2
• 化学式: C₄₄H₆₆N₂O₄P₂Ru
• 分子量: 850.037
• InChiKey: DOYLHIQYRLOKJW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cis,cis-[Ru(η2-(NO)C10H6-2-O)2(CO)2] (cis-NO, cis-O) 、 十二/十四烷基二甲基氧化胺 、 三丁基膦 以 二氯甲烷 为溶剂， 生成 trans,cis-[Ru(η2-N(O)C10H6-2-O)2(CO)((CH3)3N)] (trans-NO, cis-O) 、 trans, trans-[Ru(η2-N(O)C10H6-2-O)2(CO)(PBu3)2] (all-trans) 、 cis,cis-[Ru(η2-N(O)C10H6-2-O)2(CO)(PBu3)] (cis-NO, cis-O)
  参考文献：
  名称：

  Synthesis, characterization and crystal structure of a series of ruthenium nitrosonaphthol complexes

  摘要：

  A monosubstituted decarbonylation reaction was performed on cis-,cis-[Ru{eta(2)-N(O)C10H6O}(2)(CO)(2)] (cis-NO, cis-O) (A), trans-, cis-[Ru{eta(2)-N(O)C10H2O}(2)(CO)(2)] (trans-NO, cis-O) (B), cis-,cis-[Ru{eta(2)-OC10H6N(O)}(2)(CO)(2)] (C),trans-,cis-[Ru{eta(2)-OC10H6N(O)}(2)(CO)(2)] (D) and cis-,trans-[Ru{eta(2)-OC10H6N(O)}(2)(CO)(2)] (Cis-NO, trans-O) (E) With donor ligand (L) 4-phenylpyridine (ppy), 4-{2-(9-anthryl)vinyl}pyridine (avpy) or triphenylphosphine (PPh3) to give substituted complex cis-,cis-[Ru{eta(2)-N(O)C10H6O}(2)(CO)L] (1a, L=ppy; 2a, L=avpy; 3a, L=PPh3), trans-,cis-[Ru{eta(2)-N(O)C10H6O}(2)(CO)L] (1b, L=ppy), cis-,cis[Ru{eta(2)-OC10H6N(O)}(2)(CO)L] (Ic, L=ppy; 2c, L=avpy), trans-,cis-[Ru{eta(2)-OC10H6N(O)}(2)(CO)L] (1d, L=ppy; 2d L=avpy) or cis-,trans-[Ru{eta(2)-OC10H6N(O)}(2)(CO)L] (1e, L=ppy). Progressive substitution of the carbonyl ligands of A by tributylphosphine (PBu3) or functionalized pyridine 4-formylpyridine (fpy), 4-ethylpyridine (epy) or 4-dimethylaminopyridine (mapy) gave a centrosymmetric bisubstituted complex trans,trans-[Ru{eta(2)-N(O)C10H6O}(2)L-2] (8a, L = PBu3; 9a, L = fpy; 10a, L = epy; 11a, L = mapy) together with the corresponding mono-GO-substituted complex cis-,cis-[Ru{eta(2)-N(O)C10H6O}(2)(CO)L] (4a, L=PBu3; 5a, L=fpy; 6a, L=epy; 7a, L=mapy). The electronic absorption spectra and metal-localized oxidation formal potentials changed significantly for the bisubstituted complexes compared with the monosubstituted ones. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00317-4