[zinc(II)(4-formylantipyrine thiosemicarbazone)Cl2] monohydrate | 196105-78-9

• 英文名称: [zinc(II)(4-formylantipyrine thiosemicarbazone)Cl2] monohydrate
• CAS: 196105-78-9
• 化学式: C₁₃H₁₅Cl₂N₅OSZn*H₂O
• 分子量: 443.672
• InChiKey: RHEOVAKLLZELGN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  4-formylantipyrine thiosemicarbazone 、 zinc(II) chloride 以 甲醇 为溶剂， 生成 [zinc(II)(4-formylantipyrine thiosemicarbazone)Cl2] monohydrate
  参考文献：
  名称：

  Iron(III), Cobalt(II), Nickel(II), Copper(II) and Zinc(II) Complexes of 4-Formylantipyrine Thiosemicarbazone

  摘要：

  Complexes of iron(III), cobalt(II), nickel(II), copper(II) and zinc(II) with 4-formylantipyrine thiosemicarbazone (HFoAtsc) have been prepared and spectrally and physically characterized. IR, electronic, and ESR spectra of the complexes, as well as IR, electronic and H-1 and C-13 NMR spectra of HFoAtsc, have been obtained. The spectral studies show that HFoAtsc behaves as neutral or monobasic bidentate ligand in all complexes except [Fe(FoAtsc)(2)]ClO4 and [Co(HFoAtsc)(2)](BF4)(2), where the thiosemicarbazone bonds in a monobasic tridentate fashion in the former and a neutral tridentate manner in the latter. Coordination takes place via the azomethine nitrogen and the thione or thiolato sulfur for bidentate coordination and the carbonyl oxygen of the pyrazolone ring is added for tridentate coordination.

  DOI：

  10.1080/00945719708000252