silver;cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)-phenylphosphane;iron(2+);1,10-phenanthroline;trifluoromethanesulfonate | 219694-74-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: silver;cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)-phenylphosphane;iron(2+);1,10-phenanthroline;trifluoromethanesulfonate
• CAS: 219694-74-3
• 化学式: C₃₉H₃₁AgF₃Fe₂N₂O₃PS
• 分子量: 915.284
• InChiKey: LSCXXAUOCQOPDG-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 silver;cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)-phenylphosphane;iron(2+);trifluoromethanesulfonate 以 二氯甲烷 为溶剂， 以75%的产率得到silver;cyclopenta-1,3-diene;di(cyclopenta-2,4-dien-1-yl)-phenylphosphane;iron(2+);1,10-phenanthroline;trifluoromethanesulfonate
  参考文献：
  名称：

  Synthesis and crystallographic characterisation of silver complexes with the ligand diferrocenylphenylphosphine

  摘要：

  Diferrocenylphosphine (PFc(2)Ph) reacts with Ag(TfO) or [Ag(TfO)(PR3)] (TfO = trifluoromethanesulfonate) to afford the three-coordinate complexes [Ag(TfO)(PFc(2)Ph)(2)] or [Ag(TfO)(PFc(2)Ph)(PR3)] (PR3 = PPh2Me, PPh3), respectively. The complex [Ag(TfO)(PFc(2)Ph)(2)] further reacts with bidentate ligands, such as bis(diphenylthiophosphoryl)methane (dptpm) or S2CNEt2- leading to the cationic, [Ag(PFc(2)Ph)(2)(dptpm)]TfO, or neutral, [Ag(S2CNEt2)(PFc(2)Ph)(2)], four-coordinate complexes. The reaction with 1,10-phenanthroline (phen) gives to the four-coordinate [Ag(TfO)(PFc(2)Ph)(phen)]. (C) 1998 Elsevier Science Ltd. oil rights reserved. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(98)00129-6