diethyl 1,3-di(thiophen-2-yl)naphtho[2,3-c]thiophene-6,7-dicarboxylate | 1198206-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: diethyl 1,3-di(thiophen-2-yl)naphtho[2,3-c]thiophene-6,7-dicarboxylate
• 英文别名: Diethyl 1,3-dithiophen-2-ylbenzo[f][2]benzothiole-6,7-dicarboxylate
• CAS: 1198206-50-6
• 化学式: C₂₆H₂₀O₄S₃
• 分子量: 492.64
• InChiKey: ROPPBTKWEZYNCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  33
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  137
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  6,7-bis(thiophene-2-carbonyl)naphthalene-2,3-dicarboxylic acid diethyl ester 在 吡啶 、 tetraphosphorus decasulfide 作用下， 反应 0.33h， 以57%的产率得到diethyl 1,3-di(thiophen-2-yl)naphtho[2,3-c]thiophene-6,7-dicarboxylate
  参考文献：
  名称：

  Synthesis of Benzo[c] and Naphtho[c]heterocycle Diesters and Dinitriles via Homoelongation

  摘要：

  Syntheses of benzo[c] and naphtho[c]heterocycle diesters and dinitriles were achieved via our newly developed iterative elongation protocol. The photophysical and electrochemical properties of these conjugated systems are explored.

  DOI：

  10.1021/jo901754w

文献信息

• Synthesis of Benzo[<i>c</i>] and Naphtho[<i>c</i>]heterocycle Diesters and Dinitriles via Homoelongation
  作者：Dong-Tsou Hsu、Chih-Hsiu Lin

  DOI：10.1021/jo901754w

  日期：2009.12.4

  Syntheses of benzo[c] and naphtho[c]heterocycle diesters and dinitriles were achieved via our newly developed iterative elongation protocol. The photophysical and electrochemical properties of these conjugated systems are explored.