| 1194060-52-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• CAS: 1194060-52-0
• 化学式: C₄₇H₃₇F₆N₂PPdS
• 分子量: 913.274
• InChiKey: HTIHBLDDQLATHV-QREBVBPNSA-N

反应信息

• 作为产物：
  描述：

  palladium diacetate 、 (7Z,11Z)-2,2,17,17-tetramethyl-24-phenyl-7,12-bis[4-(trifluoromethyl)phenyl]-26-thia-25,27-diaza-24-phosphahexacyclo[16.5.1.13,6.18,11.113,16.019,23]heptacosa-1(23),3,5,7,9,11,13,15,18-nonaene 以 甲醇 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Meso-Substituent Effects on Redox Properties of the 5,10-Porphodimethene-Type P,S,N₂-Hybrid Calixphyrins and Their Metal Complexes

  摘要：

  The 5,10-porphodimethene-type P,S,N-2-hybrid calixphyrins bearing p-methoxyphenyl or p-(trifluoromethyl)phenyl groups at the sp(2)-hybridized meso carbons and their palladium(II) and rhodium(l) complexes were prepared and characterized. The electronic effects of the meso-aryl substituents on the redox properties of the pi-conjugated Subunits were evaluated for both the free bases and the palladium complexes, and the hemilabile nature of the P,S,N-2-Calixphyrin platforms in the rhodium complexes was revealed.

  DOI：

  10.1021/om900745t