申请人:——
公开号:US20020037980A1
公开(公告)日:2002-03-28
The present invention relates to a method for producing a polymer and copolymer of ethylene, and more particularly to a method for producing an ethylene polymer and copolymer by reacting a compound of an organic metal of Group II or m on the periodic table of elements with an alkoxy silane compound in the presence of a titanium catalyst, the said titanium catalyst being produced by a process of preparing a magnesium compound by contact-reacting a halogenated magnesium compound and alcohol, of reacting the said solution with an ester compound which contains at least one hydroxy group and a silicon compound containing an alkoxy group, and also of reacting it with a solid matter obtained by reaction of a mixture of a titanium compound and a silicon compound with a titanium compound. The catalyst used in polymerization and copolymerization of ethylene in the present invention is high in catalytic activity, and the polymer produced by the use of this catalyst has the merits of a high bulk density and a narrow molecular weight distribution.
本发明涉及一种生产乙烯聚合物和共聚物的方法,特别是涉及一种在钛催化剂存在下,使元素周期表中Ⅱ族或m族有机金属化合物与烷氧基硅烷化合物反应,生产乙烯聚合物和共聚物的方法、上述钛催化剂的制备方法是:通过卤化镁化合物和醇的接触反应制备镁化合物,将上述溶液与含有至少一个羟基的酯化合物和含有一个烷氧基的硅化合物反应,并与通过钛化合物和硅化合物的混合物与钛化合物反应而得到的固体物质反应。本发明中用于乙烯聚合和共聚的催化剂具有很高的催化活性,使用这种催化剂生产的聚合物具有体积密度高和分子量分布窄的优点。