[Di(propan-2-yl)phosphorylamino]-di(propan-2-yl)-sulfidophosphanium | 234766-47-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机硫代磷酸及其衍生物
• 英文名称: [Di(propan-2-yl)phosphorylamino]-di(propan-2-yl)-sulfidophosphanium
• CAS: 234766-47-3
• 化学式: C₁₂H₂₉NOP₂S
• 分子量: 297.382
• InChiKey: JOFBJTUIIAPVBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  17
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.1
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  zinc carbonate hydroxide monohydrate 、 [Di(propan-2-yl)phosphorylamino]-di(propan-2-yl)-sulfidophosphanium 以 二氯甲烷 为溶剂， 以87%的产率得到Zn[((CH₃)2CH)2P(O)NP(S)(CH(CH₃)2)2]2
  参考文献：
  名称：

  The preparation and coordination chemistry of iPr2P(E)NHP(E′)iPr2 (E, E′=Se; E=Se, E′=S; E=S, E′=O; E,E′=O

  摘要：

  Reaction of (Pr2PCl)-Pr-i with (Me3Si)(2)NH gives (Pr2PNHPPr2)-Pr-i-P-i (not isolated) which was oxidised with sulfur/selenium/oxygen to give (Pr2P)-Pr-i(E)NHP(E')Pr-i(2) (E, E'=Se; E=Se, E'=S; E=S, E'=O; E,E'=O). These neutral LH molecules readily undergo deprotonation/complexation to form simple ML, species and demonstrative examples with Zn, Cd, Pd, Pt are reported. The X-ray structure of two examples of (Pr2P)-Pr-i(E)NHP(E')Pr-i(2) (E, E' = Se, E,EI = O) are reported. The molecules pack into infinite chains via H...E Hydrogen bonds. The X-ray structures of three typical metal complexes which illustrate tetrahedral (Cd[((Pr2PSe)-Pr-i)(2)](2)) and square planar (Pt[N((Pr2PSe)-Pr-i)(2)](2)) coordination at the metal centre as well as the ability of the ME2P2N ring to adopt the pseudo-chair conformation (Pt[(Pr2P)-Pr-i(Se)NHP(S)Pr-i(2)](2)) are also reported. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00087-0

文献信息

• Synthesis and structural characterization of gallium and indium complexes obtained from redistribution reactions of mixed chalcogen-imidodiphosphinate ligands
  作者：Mónica Moya-Cabrera、Raymundo Cea-Olivares、Jocelyn Alcántara-García、Rubén A. Toscano、Vojtech Jancik、Verónica García-Montalvo、Simón Hernández-Ortega

  DOI：10.1016/j.jorganchem.2005.03.042

  日期：2005.6

  The ionic complex [GaN(SP'Pr-2)(SeP'Pr-2)-S, Se}(2)](+)[GaCl4](-) (5) was prepared by a ligand redistribution process from the monochelate Cl2GaN(SP'Pr-2)(SeP'Pr-2)-S,Se}] (3) complex in benzene. A similar phenomenon was observed for the heavier indium homologues, where the neutral complexes [ClInN(SP'Pr-2)(SeP'Pr-2)-S, Se}(2)] (7) and [ClInN(OP'Pr-2)(SP'Pr-2)-O, S}(2)] (8) were isolated along with InCl3 as the main reaction by-product. Complexes 5, 7 and 8 were characterized by single-crystal X-ray structural analysis. (c) 2005 Elsevier B.V. All rights reserved.