bis(3-aminopyridine-κN)(4,4'-dimethyl-2,2'-bipyridine-κ2N,N')(perchlorato-κO)copper(II) perchlorate | 932391-56-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: bis(3-aminopyridine-κN)(4,4'-dimethyl-2,2'-bipyridine-κ2N,N')(perchlorato-κO)copper(II) perchlorate
• 英文别名: Bis(3-aminopyridine-kappaN)(4,4-dimethyl-2,2'-bipyridine-kappa^2^N,N')(perchlorato-kappaO)copper(II) perchlorate；copper;4-methyl-2-(4-methylpyridin-2-yl)pyridine;pyridin-3-amine;diperchlorate
• CAS: 932391-56-5
• 化学式: C₂₂H₂₄ClCuN₆O₄*ClO₄
• 分子量: 634.92
• InChiKey: PXSOXYVBDHOXRV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -5.43
• 重原子数：
  39
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  252
• 氢给体数：
  2
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  3-氨基吡啶 、 4,4'-二甲基-2,2'-联吡啶 、 copper(II) perchlorate hexahydrate 以 甲醇 为溶剂， 以77%的产率得到bis(3-aminopyridine-κN)(4,4'-dimethyl-2,2'-bipyridine-κ2N,N')(perchlorato-κO)copper(II) perchlorate
  参考文献：
  名称：

  Bis(3-aminopyridine-κN)(4,4′-dimethyl-2,2′-bipyridine-κ²N,N′)(perchlorato-κO)copper(II) perchlorate

  摘要：

  The title compound, [Cu(ClO4)(C5H6N2)(2)(C12H12N2)] ClO4, was prepared by in situ partial ligand substitution between 3-aminopyridine and 4,4'-dimethyl-2, 20-bipyridine at room temperature. The central copper(II) ion is five-coordinated by one bidentate 4,4'-dimethyl-2,2'-bipyridine molecule, two monodentate pyridine-coordinated 3-aminopyridine molecules and one apical O atom from the perchlorate counterion. Intermolecular N-(HO)-O-... and C-(HO)-O-... hydrogen-bonding interactions form a hydrogen-bond-sustained network.

  DOI：

  10.1107/s0108270106021160