| 162560-79-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 162560-79-4
• 化学式: C₅₈H₆₆N₈NiO₆
• 分子量: 1029.9
• InChiKey: BKLDOZKJUCTPBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 5,6,7,8-四(亚甲基)-双环[2.2.2]-2-辛烯 以 甲苯 为溶剂， 以78%的产率得到
  参考文献：
  名称：

  [60]富勒烯与酞菁和半卟啉的Diels-Alder加合物的合成和电化学

  摘要：

  AbstractThe synthesis of a new Diels‐Alder adduct 7 of [60]fullerene and a phthalocyaninenickel compound containing a longer spacer than the originally reported Diels‐Alder adduct 1 is described. The bisenophilic hemiporphyrazinenickel compound 11 reacts with [60]fullerene to form a Diels‐Alder adduct 12 containing two fullerene units. Spectroelectrochemical investigations of 7 and 12 reveal multiple reductions, which are attributed to the corresponding subunits of the molecules. In contrast to 1, the election acceptor properties of the [60]fullerene unit in both molecules have no influence on the electronic properties of the phthalocyanine and hemiporphyrazine, respectively.

  DOI：

  10.1002/cber.19971301005
• 作为产物：
  描述：

  2,6-二氨基吡啶 、 6,7-dicyano-1,4-dihydro-1,4-di(pentyloxymethyl)-1,4-epoxynaphthalene 、 nickel diacetate 以 正丁醇 为溶剂， 以27%的产率得到
  参考文献：
  名称：

  [60]富勒烯与酞菁和半卟啉的Diels-Alder加合物的合成和电化学

  摘要：

  AbstractThe synthesis of a new Diels‐Alder adduct 7 of [60]fullerene and a phthalocyaninenickel compound containing a longer spacer than the originally reported Diels‐Alder adduct 1 is described. The bisenophilic hemiporphyrazinenickel compound 11 reacts with [60]fullerene to form a Diels‐Alder adduct 12 containing two fullerene units. Spectroelectrochemical investigations of 7 and 12 reveal multiple reductions, which are attributed to the corresponding subunits of the molecules. In contrast to 1, the election acceptor properties of the [60]fullerene unit in both molecules have no influence on the electronic properties of the phthalocyanine and hemiporphyrazine, respectively.

  DOI：

  10.1002/cber.19971301005