bis((2-(2,6-diisopropylphenylimino)ethyl)naphthoxy)nickel(II) | 724703-43-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis((2-(2,6-diisopropylphenylimino)ethyl)naphthoxy)nickel(II)
• CAS: 724703-43-9
• 化学式: C₄₈H₅₂N₂NiO₂
• 分子量: 747.643
• InChiKey: DDHIHQDPTVVEJP-NMVYOYMWSA-L

反应信息

• 作为产物：
  描述：

  trans-chloro(phenyl)bis(triphenylphosphine)nickel(II) 、 (2-[(2,6-diisopropyl-phenylimino)ethyl]naphthol) sodium salt 以 苯 为溶剂， 以86%的产率得到bis((2-(2,6-diisopropylphenylimino)ethyl)naphthoxy)nickel(II)
  参考文献：
  名称：

  Synthesis, spectroscopy and molecular structures of new salicylketiminato nickel(II) complexes

  摘要：

  A series of salicylketimines (2-[(2,6-diisopropylphenylimino)ethyl]phenol, 2-[(2,6-diisopropylphenylimino)ethyl]naphthol and 2-[(2,6-diisopropylphenylimino)(phenyl)-methyl]phenol), and their nickel complexes of general forms [(salicylketiminato)-Ni (PPh3)(Ph)] and [(salicylketiminato)(2)Ni] were synthesized and characterized. The formation of monophenyl-nickel(II) complexes versus the corresponding bis(sal)Ni(II) complexes depends on the fine tuning of the reaction work up and is affected by the substituent at the ketimine. Salicylketimines were thus found to form more readily the bis(sal)Ni(II) complexes than salicylaldimines. The molecular structures of the complexes were determined by X-ray crystallography and in all of them Ni has a nearly ideal square-planar coordination sphere. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.03.018