[(65)Cu(taa)2(dmf)]2 | 809232-72-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二噻烷
• 英文名称: [(65)Cu(taa)2(dmf)]2
• 英文别名: [(65)Cu(2-thiopheneacetate)2(DMF)]2
• CAS: 809232-72-2
• 化学式: C₃₀H₃₄Cu₂N₂O₁₀S₄
• 分子量: 840.871
• InChiKey: LGEPVYUAOOMDHN-PGHZMFPYSA-J

反应信息

• 作为产物：
  描述：

  N,N-二甲基甲酰胺 、 [((63)copper(II))2(2-thiophenacetate)4]n 以 N,N-二甲基甲酰胺 为溶剂， 生成 [(65)Cu(taa)2(dmf)]2
  参考文献：
  名称：

  New binuclear copper(II) complex with 2-thiopheneacetic acid. Synthesis, X-ray diffraction and vibrational studies of bis(N,N-dimethylformamide)tetra(2-thiopheneacetato)dicopper(II)

  摘要：

  Green crystals of the [Cu(taa)(2)(dmf)](2) (where taa denotes 2-thiopheneacetate anion) complex crystallize from the dmf solution of another polymeric [Cu-2(taa)(4)](n) complex. Obtained compound was investigated by X-ray diffraction methods, which revealed that the complex consists of centrosymmetric dimers where the bidentate 2-thiopheneacetate anions form syn, syn bridges between copper(II) ions. The coordination polyhedron of each metal ion is completed by the dmf molecule. The complex structure is well reflected in the infrared spectrum, where the assignment of the bands originating from the Cu-COO and Cu-dmf vibrations was confirmed with the aid of metal isotope substitution. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.06.034