| 1431793-46-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• CAS: 1431793-46-2
• 化学式: C₁₅H₁₄O₂
• 分子量: 226.275
• InChiKey: SOMYDTPBDSWJCO-ZZXKWVIFSA-N

反应信息

• 作为产物：
  描述：

  在 三乙胺 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以71%的产率得到
  参考文献：
  名称：

  Controlled synthesis of 1-vinylnaphthalenes versus (E)-α-(1,3-enyn-4-yl)-α,β-unsaturated esters from Morita–Baylis–Hillman bromides: a sequential alkynylation and competitive 6π-electrocyclization versus conjugative transposition of a triple bond

  摘要：

  An expedient controlled synthesis of 1-vinylnaphthalenes and various dienyne derivatives has been carried out from the Morita-Baylis-Hillman bromides and propargyl acetate or p-nitrophenyl propargyl ether. By judicious choice of base, reaction temperature, and leaving group, a selective synthesis of 1-vinylnaphthalenes and dienynes, (E)-alpha-(1,3-enyn-4-yl)-alpha,beta-unsaturated esters, could be performed. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.03.007