Deuteriooxy nitrite | 211820-10-9

• 分子结构分类: 无机化合物 - 均质非金属化合物 - 均质其他非金属化合物
• 英文名称: Deuteriooxy nitrite
• CAS: 211820-10-9
• 化学式: HNO₃
• 分子量: 64.0049
• InChiKey: CMFNMSMUKZHDEY-DYCDLGHISA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  58.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  硝酸-d 以 solid matrix 为溶剂， 生成 Deuteriooxy nitrite
  参考文献：
  名称：

  固体氩中硝酸的光解：过氧亚硝酸（HOONO）的红外吸收

  摘要：

  Nitric acid (HONO2) in solid argon at 12 K was irradiated with ultraviolet light from various sources. Recombination of the fragments OH and NO2 from photolysis within the argon lattice site has led to the formation of peroxynitrous acid (HOONO). IR absorption lines at 3545.5, 1703.6, 1364.4, 952.0, and 772.8 cm-1 have been assigned to this molecule on the basis of isotopic shifts. Under certain conditions the lines at 3563.3, 1708.3, 1372.7, 957.4, and 782.9 cm-1 were also observed, and they have been attributed to HOONO in a less stable matrix site. The observed vibrational frequencies are in agreement with recent theoretical calculations on HOONO. The implication of the formation of HOONO from HONO2 to atmospheric chemistry is also discussed.

  DOI：

  10.1021/j100160a034