N,N-(diethylamino)dithiocarbamoylbenzyl(trimethoxy)silane | 258352-22-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N,N-(diethylamino)dithiocarbamoylbenzyl(trimethoxy)silane
• 英文别名: [4-(Trimethoxysilyl)phenyl]methyl diethylcarbamodithioate；(4-trimethoxysilylphenyl)methyl N,N-diethylcarbamodithioate
• CAS: 258352-22-6
• 化学式: C₁₅H₂₅NO₃S₂Si
• 分子量: 359.586
• InChiKey: VLMJAIFGXGNLHR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.63
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  88.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4-(氯甲基)苯基三甲氧基硅烷 、 sodium N,N-diethyldithiocarbamate 以 四氢呋喃 为溶剂， 生成 N,N-(diethylamino)dithiocarbamoylbenzyl(trimethoxy)silane
  参考文献：
  名称：

  Laser Writing of Block‐Copolymer Images into Mesopores Using SBDC‐Initiated Visible‐Light‐Induced Polymerization

  摘要：

  AbstractFor miniaturization, as well as for improving artificial nanopore performance, precise local polymer functionalization and the combination of different functionalities are required. Imagining data driven nanopore design automated nanopore functionalization would be beneficial. Using direct laser writing as one option of automated nanopore polymer functionalization visible light induced polymerizations are beneficial. Here, we demonstrate the functionalization of mesoporous silicafilms with two different polymers using automated laser writing. For this we developed a visible light (400–700 nm and 405 nm) N,N(diethylamino)dithiocarbamoylbenzyl(trimethoxy)silane (SBDC) inifierter initiated polymerization. While transferring this visible light induced polymerization using SBDC to a commercially available microscope, direct, automated laser writing, as well as polymer re‐initiation was demonstrated. Thereby, polymer spots of 37 and 40 μm in diameter were achieved using 1–5 seconds for each irradiated spot.

  DOI：

  10.1002/anie.202217806

文献信息

• Laser Writing of Block‐Copolymer Images into Mesopores Using SBDC‐Initiated Visible‐Light‐Induced Polymerization
  作者：Claire Förster、Robert Lehn、Enis Musa Saritas、Annette Andrieu‐Brunsen

  DOI：10.1002/anie.202217806

  日期：——

  AbstractFor miniaturization, as well as for improving artificial nanopore performance, precise local polymer functionalization and the combination of different functionalities are required. Imagining data driven nanopore design automated nanopore functionalization would be beneficial. Using direct laser writing as one option of automated nanopore polymer functionalization visible light induced polymerizations are beneficial. Here, we demonstrate the functionalization of mesoporous silicafilms with two different polymers using automated laser writing. For this we developed a visible light (400–700 nm and 405 nm) N,N(diethylamino)dithiocarbamoylbenzyl(trimethoxy)silane (SBDC) inifierter initiated polymerization. While transferring this visible light induced polymerization using SBDC to a commercially available microscope, direct, automated laser writing, as well as polymer re‐initiation was demonstrated. Thereby, polymer spots of 37 and 40 μm in diameter were achieved using 1–5 seconds for each irradiated spot.