1-(2,5-Dimethyl-4-naphthalen-1-ylphenyl)naphthalene | 1401514-51-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(2,5-Dimethyl-4-naphthalen-1-ylphenyl)naphthalene
• CAS: 1401514-51-9
• 化学式: C₂₈H₂₂
• 分子量: 358.483
• InChiKey: MYAMNUACCUTDLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  28
• 可旋转键数：
  2
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,4-二碘-2,5-二甲苯 、 1-萘硼酸 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 5.0h， 以89%的产率得到1-(2,5-Dimethyl-4-naphthalen-1-ylphenyl)naphthalene
  参考文献：
  名称：

  Immobilized palladium nanoparticles on silica–starch substrate (PNP–SSS): As a stable and efficient heterogeneous catalyst for synthesis of p-teraryls using Suzuki reaction

  摘要：

  Immobilized palladium nanoparticles on silica-starch substrate (PNP-SSS) were found to be an efficient reusable catalyst for excellent synthesis of teraryls using Suzuki reaction. The catalytic reactivity of PNP-SSS was examined over a set of substrates, demonstrating that it is reactive toward a variety of functionalities. In this process, the PNP-SSS catalyst can be reused more than six times with almost consistent efficiency and can be recovered by simple filtration. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.07.039

文献信息

• Immobilized palladium nanoparticles on silica–starch substrate (PNP–SSS): As a stable and efficient heterogeneous catalyst for synthesis of p-teraryls using Suzuki reaction
  作者：Ali Khalafi-Nezhad、Farhad Panahi

  DOI：10.1016/j.jorganchem.2012.07.039

  日期：2012.10

  Immobilized palladium nanoparticles on silica-starch substrate (PNP-SSS) were found to be an efficient reusable catalyst for excellent synthesis of teraryls using Suzuki reaction. The catalytic reactivity of PNP-SSS was examined over a set of substrates, demonstrating that it is reactive toward a variety of functionalities. In this process, the PNP-SSS catalyst can be reused more than six times with almost consistent efficiency and can be recovered by simple filtration. (C) 2012 Elsevier B. V. All rights reserved.