3-Ethylselanylpropan-1-ol | 189247-80-1

• 分子结构分类: 有机化合物 - 有机金属化合物
• 英文名称: 3-Ethylselanylpropan-1-ol
• CAS: 189247-80-1
• 化学式: C₅H₁₂OSe
• 分子量: 167.11
• InChiKey: NIAJZIXZIBFORS-UHFFFAOYSA-N

物化性质

• 沸点：
  226.9±23.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.93
• 重原子数：
  7
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-Ethylselanylpropan-1-ol 在 2-chloro-2-phenyl-1,2-oxaselenurolane 作用下， 以 二氯甲烷 为溶剂， 以99%的产率得到2-chloro-2-ethyl-1,2-oxaselenurolane
  参考文献：
  名称：

  Reactivity of Chlorooxachalcogenuranes: Oxidation of Sulfides to Sulfoxides Using Chlorooxaselenuranes

  摘要：

  The transformation of chloro between chlorooxachalcogenuranes 3 and chalcogenides 4 is described. The oxidative ability of chlorooxachalcogenuranes has been compared. Selenuranes 3a, b have been found to be good reagents for selective oxidation of sulfides to sulfoxides under mild conditions.

  DOI：

  10.1080/00397910008087115
• 作为产物：
  描述：

  2-chloro-2-ethyl-1,2-oxaselenurolane 在 3-(methyltellanyl)propan-1-ol 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 生成 3-Ethylselanylpropan-1-ol
  参考文献：
  名称：

  Reactivity of Chlorooxachalcogenuranes: Oxidation of Sulfides to Sulfoxides Using Chlorooxaselenuranes

  摘要：

  The transformation of chloro between chlorooxachalcogenuranes 3 and chalcogenides 4 is described. The oxidative ability of chlorooxachalcogenuranes has been compared. Selenuranes 3a, b have been found to be good reagents for selective oxidation of sulfides to sulfoxides under mild conditions.

  DOI：

  10.1080/00397910008087115

文献信息

• Zhang, Jian; Saito, Shinichi; Takahashi, Tamiko, Heterocycles, 1997, vol. 45, # 3, p. 575 - 584
  作者：Zhang, Jian、Saito, Shinichi、Takahashi, Tamiko、Koizumi, Toru

  DOI：——

  日期：——
• One-Pot Two-Step Approach to Selenides. Phase-Transfer Catalyzed Synthesis of ω-Hydroxyalkyl Selenides
  作者：Xubo Hu、Zhenjiao Tian、Yuanyin Chen、Xueran Lu

  DOI：10.1080/00397910008087348

  日期：2000.2

  omega-hydroxyalkyl selenides were synthesized in good yields under phase-transfer conditions which involved hadrazine reduction on selenium powder and then alkylation with omega-haloalkyl alcohols in the presence of TBAB, reduction the resulting diselenides with KBH4 followed by treatment with alkyl halides.