(E)-dimethyl(6-methyl-1-phenylhept-4-en-3-yl)(phenyl)silane | 1384985-29-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (E)-dimethyl(6-methyl-1-phenylhept-4-en-3-yl)(phenyl)silane
• 英文别名: dimethyl-[(E)-6-methyl-1-phenylhept-4-en-3-yl]-phenylsilane
• CAS: 1384985-29-8
• 化学式: C₂₂H₃₀Si
• 分子量: 322.566
• InChiKey: HXIIAWQZUMUVJD-BMRADRMJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.82
• 重原子数：
  23
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  苯乙烯 在 potassium tert-butylate 、 copper (I) acetate 作用下， 以 四氢呋喃 为溶剂， 反应 7.0h， 生成 (E)-dimethyl(6-methyl-1-phenylhept-4-en-3-yl)(phenyl)silane
  参考文献：
  名称：

  Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes

  摘要：

  A copper-catalyzed gamma-selective allyl-alkyl coupling between gamma-silylated allylic phosphates and alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) produced allylsilanes. The reaction tolerated various functional groups in both the alkylboranes and the allylic phosphates, and afforded functionalized allylsilanes.

  DOI：

  10.1055/s-0031-1290818

文献信息

• Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed γ-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes
  作者：Hirohisa Ohmiya、Masaya Sawamura、Kazunori Nagao

  DOI：10.1055/s-0031-1290818

  日期：2012.5

  A copper-catalyzed gamma-selective allyl-alkyl coupling between gamma-silylated allylic phosphates and alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) produced allylsilanes. The reaction tolerated various functional groups in both the alkylboranes and the allylic phosphates, and afforded functionalized allylsilanes.