[Cu(salicylaldehyde-3-hexamethyleneiminyl thiosemicarbazone(-1H))2] | 163231-66-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: [Cu(salicylaldehyde-3-hexamethyleneiminyl thiosemicarbazone(-1H))2]
• CAS: 163231-66-1
• 化学式: C₂₄H₂₈CuN₆O₂S₂
• 分子量: 560.203
• InChiKey: FCLFRDORDVRNED-YJCYQSLBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  salicylaldehyde 3-tetramethyleneiminyl thiosemicarbazone 、 copper(II) acetate monohydrate 以 乙醇 、 水 为溶剂， 生成 [Cu(salicylaldehyde-3-hexamethyleneiminyl thiosemicarbazone(-1H))2]
  参考文献：
  名称：

  Spectral and structural studies of copper(II) complexes of thiosemicarbazones derived from salicylaldehyde and containing ring incorporated at N(4)-position

  摘要：

  Mononuclear and binuclear copper(II) complexes (1-8) with two ONS donor thiosemicarbazone ligands {salicylaldehyde3-hexamethyleneiminyl thiosemicarbazone [H2L1] and salicylaldehyde 3-tetramethyleneiminyl thiosemicarbazone [H2L2]} have been prepared and physico-chemically characterized. IR, electronic and EPR spectra of the complexes have been obtained. The thiosemicarbazones bind to metal as dianionic ONS donor ligands in all the complexes except in [Cu(HL1)(2)] (2) and [Cu(HL2)(2)] (6). In compounds 2 and 6 the ligands are coordinated as monoanionic HL- ones. The magnetic susceptibility measurements indicate that all the complexes are paramagnetic. In complex [(CuL1)(2)] (1), the magnetic moment value is lower than the expected spin only value. In all the complexes g(parallel to) > g(perpendicular to) > 2.0023 and G values within the range 2.5-3.5 are consistent with d(x2-y2) ground state. The complexes were given the formula as [(CuL1)(2)] (1); [Cu(HL1)(2)] (2); [CuL(1)bpy] (3); [CuL(1)phen] (4); [CuL1-gamma-pic]center dot 2H(2)O (5); [Cu(HL2)(2)] (6); [CuL(2)py]center dot 3H(2)O (7); [CuL(2)bipy] (8). The structure of the compound 8 have been solved by single crystal X-ray crystallography and was found to be distorted square pyramid around copper(II) ion. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.saa.2007.07.015