[1,8-C10H6(NSi(i)BuMe2)2]TiCl2 | 216015-48-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [1,8-C10H6(NSi(i)BuMe2)2]TiCl2
• 英文别名: [Tert-butyl(dimethyl)silyl]-[8-[tert-butyl(dimethyl)silyl]azanidylnaphthalen-1-yl]azanide;titanium(4+);dichloride
• CAS: 216015-48-4
• 化学式: C₂₂H₃₆Cl₂N₂Si₂Ti
• 分子量: 503.498
• InChiKey: GOKHNJZEXFMHRD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.87
• 重原子数：
  29
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,8-C10H6(NLiSi(i)BuMe2)2 、 四氯化钛 以 乙醚 为溶剂， 以61%的产率得到[1,8-C10H6(NSi(i)BuMe2)2]TiCl2
  参考文献：
  名称：

  Synthesis of titanium(IV) complexes that contain the Bis(silylamide) ligand of the type [1,8-C10H6(NR)2]2−, and alkene polymerization catalyzed by [1,8-C10H6(NR)2]TiCl2-cocatalyst system

  摘要：

  [1,8-C10H6(NR)(2)]TiCl2 (3; R = SiMe3, (SiBuMe2)-Bu-i, (SiPr3)-Pr-i) complexes have been prepared from dilithio salts [1,8-C10H6(NR)(2)]Li-2 (2) and TiCl4 in diethyl ether in moderate yields (60-63%), These complexes showed significant catalytic activities for ethylene polymerization and for ethylene/1-hexene copolymerization in the presence of methylaluminoxane (MAO), methyl isobutyl aluminoxane (MMAO), (AlBu3)-Bu-i- or AlEt3-Ph3CB(C6F5)(4) as a cocatalyst, The catalytic activities performed in heptane (cocatalyst MMAO) were higher than those carried out in toluene (cocatalyst MAO): 709 kg-PE/mol-Ti . h could be attained for ethylene polymerization by using [1,8-C10H6((NSiBuMe2)-Bu-i)(2)]TiCl2-MMAO catalyst system. (C) 1998 Elsevier Science B.V.

  DOI：

  10.1016/s1381-1169(97)00292-6