| 949013-00-7

• 分子结构分类: 有机化合物 - 乙炔化物
• CAS: 949013-00-7
• 化学式: CH₄Re
• 分子量: 202.25
• InChiKey: VZYJUHIPCSNOIN-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  铼 、 methane 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Formation of HC⋮ReH₃ in Methane Activation by Rhenium Atoms: Observation of the Elusive Methylidyne C−H Stretching Absorption

  摘要：

  HC ReH3 is formed in the reaction of Re atoms with CH4 in excess argon. The insertion complex is generated, and two alpha-hydrogen migrations follow to produce the trihydrido methylidyne complex HC ReH3, which has a C-s structure, a C-H stretching absorption at 3102 cm(-1), a C Re stretching mode at 1049 cm(-1), and a very strong Re-H stretching absorption at 1804 cm(-1).

  DOI：

  10.1021/om070218v