[Cu(N,N'-ethylenebis(3-ethoxysalicylaldimine(-2H))][Fe(N,N'-ethylenebis(3-ethoxysalicylaldimine(H2O)2][ClO4] | 1332303-60-2

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: [Cu(N,N'-ethylenebis(3-ethoxysalicylaldimine(-2H))][Fe(N,N'-ethylenebis(3-ethoxysalicylaldimine(H2O)2][ClO4]
• CAS: 1332303-60-2
• 化学式: C₂₀H₂₂CuN₂O₄*C₂₀H₂₆FeN₂O₆*ClO₄
• 分子量: 963.686
• InChiKey: BHGSGHJCHOIGPY-ZBBCSWSTSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  水 、 [Cu(II)(N,N′-ethylenebis(3-ethoxysalicylaldimine))(H₂O)] 、 iron(II) perchlorate hexahydrate 以 甲醇 、 乙腈 为溶剂， 以75%的产率得到[Cu(N,N'-ethylenebis(3-ethoxysalicylaldimine(-2H))][Fe(N,N'-ethylenebis(3-ethoxysalicylaldimine(H2O)2][ClO4]
  参考文献：
  名称：

  Syntheses, crystal structures and magnetic properties of [2×1+1×2] heterotetrametallic and [1×1+1×1] heterodimetallic cocrystals of copper(II) and iron(II/III)

  摘要：

  The present work reports syntheses, crystal structures and variable-temperature magnetic properties of three copper(II)-iron(II/III) compounds [{(CuL1)-L-II}{(FeL1)-L-III(H2O)(2)}](ClO4) (1), [{(CuLFeII)-L-II-Fe-1(H2O)(3)}{(CuL1)-L-II}(2)](-ClO4)(2) (2) and [{(CuLFeII)-L-II-Fe-2(H2O)(3)}{(CuL2)-L-II}(2)](ClO4)(2)center dot H2O center dot CH3COCH3 (3), where H2L1 = N,N'-ethylenebis(3-ethoxysalicylaldimine) and H2L2 = N,N'-o-phenylenebis(3-ethoxysalicylaldimine). Compounds 2 and 3 are tetrametallic [2 x 1 + 1 x 2] cocrystals of one diphenoxo-bridged dinuclear (CuFeII)-Fe-II and two mononuclear Cu-II moieties, while compound 1 is a dimetallic [1 x 1 + 1 x 1] cocrystal of one mononuclear Fe-III and one mononuclear CuII moieties. The overall topology of 1 is one-dimensional. Tetrametallic (in 2 and 3) and one-dimensional (in 1) self-assemblies are generated due to weak noncovalent interactions. Variable-temperature magnetic susceptibility measurements reveal that iron(II) or iron(III) centers in 1-3 remain in high-spin state. Compounds 2 and 3 exhibit weak antiferromagnetic interaction; the J values in the dinuclear core are -22.5 and -13.7 cm (1), respectively, compound 1 exhibits very weak antiferromagnetic interaction (J = -0.25 cm (1)) propagated through the weak noncovalent bonds. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.05.015